Ni-catalyzed reductive coupling of α-halocarbonyl derivatives with vinyl bromidesElectronic supplementary information (ESI) available. See DOI: 10.1039/c6ob02269c

This work describes the vinylation of α-halo carbonyl compounds with vinyl bromides under Ni-catalyzed reductive coupling conditions. While aryl-conjugated vinyl bromides entail pyridine as the sole labile ligand, the alkyl-substituted vinyl bromides require both bipyridine and pyridine as the co-li...

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Bibliographic Details
Main Authors: Qiu, Canbin, Yao, Ken, Zhang, Xinghua, Gong, Hegui
Format: Article
Language:English
Online Access:Get full text
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Summary:This work describes the vinylation of α-halo carbonyl compounds with vinyl bromides under Ni-catalyzed reductive coupling conditions. While aryl-conjugated vinyl bromides entail pyridine as the sole labile ligand, the alkyl-substituted vinyl bromides require both bipyridine and pyridine as the co-ligands. This work describes the vinylation of α-halo carbonyl compounds with vinyl bromides under Ni-catalyzed reductive coupling conditions. While aryl-conjugated vinyl bromides entail pyridine as the sole labile ligand, the alkyl-substituted vinyl bromides require both bipyridine and pyridine as the co-ligands.
ISSN:1477-0520
1477-0539
DOI:10.1039/c6ob02269c