Ni-catalyzed reductive coupling of α-halocarbonyl derivatives with vinyl bromidesElectronic supplementary information (ESI) available. See DOI: 10.1039/c6ob02269c

This work describes the vinylation of α-halo carbonyl compounds with vinyl bromides under Ni-catalyzed reductive coupling conditions. While aryl-conjugated vinyl bromides entail pyridine as the sole labile ligand, the alkyl-substituted vinyl bromides require both bipyridine and pyridine as the co-li...

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Main Authors: Qiu, Canbin, Yao, Ken, Zhang, Xinghua, Gong, Hegui
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Gong, Hegui
description This work describes the vinylation of α-halo carbonyl compounds with vinyl bromides under Ni-catalyzed reductive coupling conditions. While aryl-conjugated vinyl bromides entail pyridine as the sole labile ligand, the alkyl-substituted vinyl bromides require both bipyridine and pyridine as the co-ligands. This work describes the vinylation of α-halo carbonyl compounds with vinyl bromides under Ni-catalyzed reductive coupling conditions. While aryl-conjugated vinyl bromides entail pyridine as the sole labile ligand, the alkyl-substituted vinyl bromides require both bipyridine and pyridine as the co-ligands.
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title Ni-catalyzed reductive coupling of α-halocarbonyl derivatives with vinyl bromidesElectronic supplementary information (ESI) available. See DOI: 10.1039/c6ob02269c
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