trans- and cis-(Cl,Cl)-[RuII(FT)Cl2(NO)](PF6): promising candidates for NO release in the NIR regionElectronic supplementary information (ESI) available: Details of the synthesis, X-ray structure, and photophysical, EPR, and two-photon induced NO release experiments, and cytotoxicity details. CCDC 1055811 and 1469428. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6pp00181e

cis - and trans -(Cl,Cl)-[Ru II (FT)Cl 2 (NO)](PF 6 ) complexes show efficient NO photodelivery upon two-photon excitation in the NIR region. Moreover, cytotoxicity and phototoxicity studies provide evidence that these complexes are promising candidates as photoactivatable molecular tools for resect...

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Main Authors: Akl, Joelle, Sasaki, Isabelle, Lacroix, Pascal G, Hugues, Vincent, Vicendo, Patricia, Bocé, Mathilde, Mallet-Ladeira, Sonia, Blanchard-Desce, Mireille, Malfant, Isabelle
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Language:English
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Summary:cis - and trans -(Cl,Cl)-[Ru II (FT)Cl 2 (NO)](PF 6 ) complexes show efficient NO photodelivery upon two-photon excitation in the NIR region. Moreover, cytotoxicity and phototoxicity studies provide evidence that these complexes are promising candidates as photoactivatable molecular tools for resection of malignancies. Efficient NO photodelivery from cis - and trans -(Cl,Cl)-[Ru II (FT)Cl 2 (NO)](PF 6 ) complexes upon two-photon excitation in the NIR region.
ISSN:1474-905X
1474-9092
DOI:10.1039/c6pp00181e