Green light-emitting 2-(1H-indol-3-yl)acetonitrile-based D-A fluorophores - a combined theoretical and experimental studyElectronic supplementary information (ESI) available: Absorption and emission spectra of all the compounds in different solvents, absorption spectra of the thin films, results of the fluorescence decay in different solvents, cyclic voltammogram results, AFM images for all the compounds, DFT optimized structures, lifetime data for all the solvents, frontier molecular orbital en

• Main Authors: Muruganantham, Subramanian, Nagarajan, Natarajan, Velmurugan, Gunasekaran, Prakash, Asit, Katiyar, Monica, Venuvanalingam, Ponnambalam, Renganathan, Rajalingam
• Format: Article
• Language: English
• ISSN: 2052-1537
• DOI: 10.1039/c6qm00326e

A series of new fluorophores based on 2-(1 H -indol-3-yl)acetonitrile incorporated with various polycyclic aromatic hydrocarbons, carbazole, pyridine, and triphenylamine was designed and synthesised. The optical, electrochemical, thermal, and morphological properties of the fluorophores were studied using various spectroscopic techniques. The demonstration of electroluminescence behaviour was carried out by fabricating a single layer device with the device structure of indium tin oxide (ITO - 150 nm)/poly(ethylenedioxythiophene)-polystyrene sulfonate (PEDOT:PSS - 40 nm)/emissive layer (65 nm)/lithium fluoride (LiF - 0.5 nm)/Al (120 nm), which exhibited a turn-on voltage of 6.5 V, maximum brightness of 110 cd m −2 and 133 cd m −2 , maximum current efficiency of 0.34 cd A −1 and 0.73 cd A −1 , and power efficiency of 0.10 lm W −1 and 0.28 lm W −1 for TIN and T2IN , respectively. Density functional theory (DFT) results revealed that the highest occupied molecular orbital (HOMO) is mainly localized on the donor part, whereas the lowest unoccupied molecular orbital (LUMO) is spread over the entire molecule i.e. over the donor, π-spacer, and acceptor units. The higher HOMO and lower LUMO energies of fluorophores reduce the energy barrier for hole creation and electron acceptance processes, respectively. All the fluorophores show a narrow band gap, and the charge injection ability increases with suitable substitution, which leads to improved organic light-emitting diode (OLED) performance. A series of new fluorophores based on 2-(1 H -indol-3-yl)acetonitrile incorporated with various polycyclic aromatic hydrocarbons, carbazole, pyridine, triphenylamine was synthesised and their optical, thermal, electrochemical properties were evaluated.