Loading…
Solid state conversion of a double helix thallium() coordination polymer to a corrugated tape silver() polymer
We observed the solid state conversion of a nanostructured Tl I coordination polymer with a double helix chain structure, prepared by a sonochemical procedure, to a nanostructured corrugated tape silver( i ) polymer via the mechanochemical reaction of [Tl( 2 -dcpa)] n ( 1 ) [Hdcpa = 2,4-dichlorophen...
Saved in:
| Published in: | RSC advances 2016-01, Vol.6 (85), p.82447-82449 |
|---|---|
| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c352t-55c27a68f50e197d419a7bb2b39c6f29ba586e0ae5d120326a3c69e5faede82c3 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c352t-55c27a68f50e197d419a7bb2b39c6f29ba586e0ae5d120326a3c69e5faede82c3 |
| container_end_page | 82449 |
| container_issue | 85 |
| container_start_page | 82447 |
| container_title | RSC advances |
| container_volume | 6 |
| creator | Moeinian, Maryam Akhbari, Kamran Kawata, Satoshi Ishikawa, Ryuta |
| description | We observed the solid state conversion of a nanostructured Tl
I
coordination polymer with a double helix chain structure, prepared by a sonochemical procedure, to a nanostructured corrugated tape silver(
i
) polymer
via
the mechanochemical reaction of [Tl(
2
-dcpa)]
n
(
1
) [Hdcpa = 2,4-dichlorophenoxyacetic acid] with AgNO
3
. The internal packing of these two compounds looked similar and low-energy structural changes allowed the conversion to occur smoothly. The transformation was irreversible as a result of the formation of stronger AgO bonds (in
2
) compared with the initial TlO bonds (in
1
). There are weak interaction planes in the crystal packing of
1
, so the structure is not mechanically rigid, which allows Ag ions to penetrate the lattice and form stronger bonds.
Irreversible solid-state conversion of Tl
I
coordination polymer with double helix chain structure to corrugated tape silver(
i
) polymer has been observed upon mechanochemical reaction of [Tl(
2
-dcpa)]
n
(
1
) with AgNO
3
. |
| doi_str_mv | 10.1039/c6ra09423f |
| format | article |
| fullrecord | <record><control><sourceid>proquest_rsc_p</sourceid><recordid>TN_cdi_rsc_primary_c6ra09423f</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1845791096</sourcerecordid><originalsourceid>FETCH-LOGICAL-c352t-55c27a68f50e197d419a7bb2b39c6f29ba586e0ae5d120326a3c69e5faede82c3</originalsourceid><addsrcrecordid>eNpN0M9LwzAUB_AiCo65i3chxylU86NJm-MYToWB4I9zSdNXF0mbmqTi_ns7N9R3ee_wed_DN0nOCb4mmMkbLbzCMqOsOUomFGcipVjI43_3aTIL4R2PIzihgkyS7tlZU6MQVQSkXfcJPhjXIdcghWo3VBbQBqz5QnGjrDVDO78cnfO16VTcyd7ZbQseRTd-aOf98DZm1SiqHlAwdkwcXw7qLDlplA0wO-xp8rq6fVnep-vHu4flYp1qxmlMOdc0V6JoOAYi8zojUuVVRSsmtWiorBQvBGAFvCYUMyoU00ICbxTUUFDNpsl8n9t79zFAiGVrggZrVQduCCUpMp5LgqUY6dWeau9C8NCUvTet8tuS4HLXa7kUT4ufXlcjvthjH_Sv--udfQNAs3XX</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1845791096</pqid></control><display><type>article</type><title>Solid state conversion of a double helix thallium() coordination polymer to a corrugated tape silver() polymer</title><source>Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)</source><creator>Moeinian, Maryam ; Akhbari, Kamran ; Kawata, Satoshi ; Ishikawa, Ryuta</creator><creatorcontrib>Moeinian, Maryam ; Akhbari, Kamran ; Kawata, Satoshi ; Ishikawa, Ryuta</creatorcontrib><description>We observed the solid state conversion of a nanostructured Tl
I
coordination polymer with a double helix chain structure, prepared by a sonochemical procedure, to a nanostructured corrugated tape silver(
i
) polymer
via
the mechanochemical reaction of [Tl(
2
-dcpa)]
n
(
1
) [Hdcpa = 2,4-dichlorophenoxyacetic acid] with AgNO
3
. The internal packing of these two compounds looked similar and low-energy structural changes allowed the conversion to occur smoothly. The transformation was irreversible as a result of the formation of stronger AgO bonds (in
2
) compared with the initial TlO bonds (in
1
). There are weak interaction planes in the crystal packing of
1
, so the structure is not mechanically rigid, which allows Ag ions to penetrate the lattice and form stronger bonds.
Irreversible solid-state conversion of Tl
I
coordination polymer with double helix chain structure to corrugated tape silver(
i
) polymer has been observed upon mechanochemical reaction of [Tl(
2
-dcpa)]
n
(
1
) with AgNO
3
.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/c6ra09423f</identifier><language>eng</language><subject>Conversion ; Coordination polymers ; Corrugating ; Mechanochemistry ; Nanostructure ; Silver ; Solid state ; Transformations</subject><ispartof>RSC advances, 2016-01, Vol.6 (85), p.82447-82449</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c352t-55c27a68f50e197d419a7bb2b39c6f29ba586e0ae5d120326a3c69e5faede82c3</citedby><cites>FETCH-LOGICAL-c352t-55c27a68f50e197d419a7bb2b39c6f29ba586e0ae5d120326a3c69e5faede82c3</cites><orcidid>0000-0002-1279-6283</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27922,27923</link.rule.ids></links><search><creatorcontrib>Moeinian, Maryam</creatorcontrib><creatorcontrib>Akhbari, Kamran</creatorcontrib><creatorcontrib>Kawata, Satoshi</creatorcontrib><creatorcontrib>Ishikawa, Ryuta</creatorcontrib><title>Solid state conversion of a double helix thallium() coordination polymer to a corrugated tape silver() polymer</title><title>RSC advances</title><description>We observed the solid state conversion of a nanostructured Tl
I
coordination polymer with a double helix chain structure, prepared by a sonochemical procedure, to a nanostructured corrugated tape silver(
i
) polymer
via
the mechanochemical reaction of [Tl(
2
-dcpa)]
n
(
1
) [Hdcpa = 2,4-dichlorophenoxyacetic acid] with AgNO
3
. The internal packing of these two compounds looked similar and low-energy structural changes allowed the conversion to occur smoothly. The transformation was irreversible as a result of the formation of stronger AgO bonds (in
2
) compared with the initial TlO bonds (in
1
). There are weak interaction planes in the crystal packing of
1
, so the structure is not mechanically rigid, which allows Ag ions to penetrate the lattice and form stronger bonds.
Irreversible solid-state conversion of Tl
I
coordination polymer with double helix chain structure to corrugated tape silver(
i
) polymer has been observed upon mechanochemical reaction of [Tl(
2
-dcpa)]
n
(
1
) with AgNO
3
.</description><subject>Conversion</subject><subject>Coordination polymers</subject><subject>Corrugating</subject><subject>Mechanochemistry</subject><subject>Nanostructure</subject><subject>Silver</subject><subject>Solid state</subject><subject>Transformations</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNpN0M9LwzAUB_AiCo65i3chxylU86NJm-MYToWB4I9zSdNXF0mbmqTi_ns7N9R3ee_wed_DN0nOCb4mmMkbLbzCMqOsOUomFGcipVjI43_3aTIL4R2PIzihgkyS7tlZU6MQVQSkXfcJPhjXIdcghWo3VBbQBqz5QnGjrDVDO78cnfO16VTcyd7ZbQseRTd-aOf98DZm1SiqHlAwdkwcXw7qLDlplA0wO-xp8rq6fVnep-vHu4flYp1qxmlMOdc0V6JoOAYi8zojUuVVRSsmtWiorBQvBGAFvCYUMyoU00ICbxTUUFDNpsl8n9t79zFAiGVrggZrVQduCCUpMp5LgqUY6dWeau9C8NCUvTet8tuS4HLXa7kUT4ufXlcjvthjH_Sv--udfQNAs3XX</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Moeinian, Maryam</creator><creator>Akhbari, Kamran</creator><creator>Kawata, Satoshi</creator><creator>Ishikawa, Ryuta</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-1279-6283</orcidid></search><sort><creationdate>20160101</creationdate><title>Solid state conversion of a double helix thallium() coordination polymer to a corrugated tape silver() polymer</title><author>Moeinian, Maryam ; Akhbari, Kamran ; Kawata, Satoshi ; Ishikawa, Ryuta</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c352t-55c27a68f50e197d419a7bb2b39c6f29ba586e0ae5d120326a3c69e5faede82c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Conversion</topic><topic>Coordination polymers</topic><topic>Corrugating</topic><topic>Mechanochemistry</topic><topic>Nanostructure</topic><topic>Silver</topic><topic>Solid state</topic><topic>Transformations</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Moeinian, Maryam</creatorcontrib><creatorcontrib>Akhbari, Kamran</creatorcontrib><creatorcontrib>Kawata, Satoshi</creatorcontrib><creatorcontrib>Ishikawa, Ryuta</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Moeinian, Maryam</au><au>Akhbari, Kamran</au><au>Kawata, Satoshi</au><au>Ishikawa, Ryuta</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solid state conversion of a double helix thallium() coordination polymer to a corrugated tape silver() polymer</atitle><jtitle>RSC advances</jtitle><date>2016-01-01</date><risdate>2016</risdate><volume>6</volume><issue>85</issue><spage>82447</spage><epage>82449</epage><pages>82447-82449</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>We observed the solid state conversion of a nanostructured Tl
I
coordination polymer with a double helix chain structure, prepared by a sonochemical procedure, to a nanostructured corrugated tape silver(
i
) polymer
via
the mechanochemical reaction of [Tl(
2
-dcpa)]
n
(
1
) [Hdcpa = 2,4-dichlorophenoxyacetic acid] with AgNO
3
. The internal packing of these two compounds looked similar and low-energy structural changes allowed the conversion to occur smoothly. The transformation was irreversible as a result of the formation of stronger AgO bonds (in
2
) compared with the initial TlO bonds (in
1
). There are weak interaction planes in the crystal packing of
1
, so the structure is not mechanically rigid, which allows Ag ions to penetrate the lattice and form stronger bonds.
Irreversible solid-state conversion of Tl
I
coordination polymer with double helix chain structure to corrugated tape silver(
i
) polymer has been observed upon mechanochemical reaction of [Tl(
2
-dcpa)]
n
(
1
) with AgNO
3
.</abstract><doi>10.1039/c6ra09423f</doi><tpages>3</tpages><orcidid>https://orcid.org/0000-0002-1279-6283</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2046-2069 |
| ispartof | RSC advances, 2016-01, Vol.6 (85), p.82447-82449 |
| issn | 2046-2069 2046-2069 |
| language | eng |
| recordid | cdi_rsc_primary_c6ra09423f |
| source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
| subjects | Conversion Coordination polymers Corrugating Mechanochemistry Nanostructure Silver Solid state Transformations |
| title | Solid state conversion of a double helix thallium() coordination polymer to a corrugated tape silver() polymer |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-13T17%3A48%3A32IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_rsc_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Solid%20state%20conversion%20of%20a%20double%20helix%20thallium()%20coordination%20polymer%20to%20a%20corrugated%20tape%20silver()%20polymer&rft.jtitle=RSC%20advances&rft.au=Moeinian,%20Maryam&rft.date=2016-01-01&rft.volume=6&rft.issue=85&rft.spage=82447&rft.epage=82449&rft.pages=82447-82449&rft.issn=2046-2069&rft.eissn=2046-2069&rft_id=info:doi/10.1039/c6ra09423f&rft_dat=%3Cproquest_rsc_p%3E1845791096%3C/proquest_rsc_p%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c352t-55c27a68f50e197d419a7bb2b39c6f29ba586e0ae5d120326a3c69e5faede82c3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1845791096&rft_id=info:pmid/&rfr_iscdi=true |