Interaction of organodialkoxysilanolates with carbon dioxideElectronic supplementary information (ESI) available. See DOI: 10.1039/c6ra19758b

A series of organo(alkoxy)disiloxanes was obtained by the reaction of carbon dioxide with sodium alkoxy(organo)silanolates under high pressure as well as by bubbling CO 2 through the reaction mixture. It has been suggested that the reaction involves the intermediate formation of carbonate derivative...

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Main Authors: Temnikov, M. N, Cherkun, N. V, Boldyrev, K. L, Zimovets, S. N, Kononova, E. G, Elmanovich, I. V, Gallyamov, M. O, Muzafarov, A. M
Format: Article
Language:English
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Summary:A series of organo(alkoxy)disiloxanes was obtained by the reaction of carbon dioxide with sodium alkoxy(organo)silanolates under high pressure as well as by bubbling CO 2 through the reaction mixture. It has been suggested that the reaction involves the intermediate formation of carbonate derivatives of sodium alkoxy(organo)silanolates. A series of organo(alkoxy)disiloxanes was obtained by the reaction of CO 2 with sodium alkoxy(organo)silanolates under high pressure. It is suggested that the reaction involves intermediate formation of the carbonate derivative of sodium alkoxy(organo)silanolates.
ISSN:2046-2069
DOI:10.1039/c6ra19758b