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Field effects to slow magnetic relaxation in a mononuclear Ni(ii) complexElectronic supplementary information (ESI) available: Details of synthesis, analysis, spectra, X-ray structure and calculations. CCDC 1540217. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7cc03275g
A mononuclear Ni( ii ) complex [Ni(NCS) 2 (nqu) 2 (H 2 O) 2 ]·2nqu (nqu - 5-nitroquinoline) shows a field induced slow magnetic relaxation with three relaxation domains. The relaxation time for the low-frequency mode is as slow as τ = 0.3 s at T = 1.9 K and B DC = 0.4 T. A mononuclear Ni( ii ) compl...
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Main Authors: | , , , , |
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Format: | Article |
Language: | English |
Online Access: | Get full text |
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Summary: | A mononuclear Ni(
ii
) complex [Ni(NCS)
2
(nqu)
2
(H
2
O)
2
]·2nqu (nqu - 5-nitroquinoline) shows a field induced slow magnetic relaxation with three relaxation domains. The relaxation time for the low-frequency mode is as slow as
τ
= 0.3 s at
T
= 1.9 K and
B
DC
= 0.4 T.
A mononuclear Ni(
ii
) complex [Ni(NCS)
2
(nqu)
2
(H
2
O)
2
]·2nqu (nqu - 5-nitroquinoline) shows a field induced slow magnetic relaxation with three relaxation domains. The relaxation time for the low-frequency mode is as slow as
τ
= 0.3 s at
T
= 1.9 K and
B
DC
= 0.4 T. |
---|---|
ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/c7cc03275g |