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New mechanistic insights into intramolecular aromatic ligand hydroxylation and benzyl alcohol oxidation initiated by the well-defined (μ-peroxo)diiron(iii) complexElectronic supplementary information (ESI) available: Experimental details of synthesis, and structural, spectroscopic, kinetic, and DFT data. CCDC 1554479. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7cc04382a
A (μ-peroxo)diiron( iii ) complex [Fe 2 (L Ph 4 )(O 2 )(Ph 3 CCO 2 )] 2+ (1-O 2 ) with a dinucleating ligand (L Ph 4 ), generated from the reaction of a carboxylate bridged diiron( ii ) complex [Fe 2 (L Ph 4 )(Ph 3 CCO 2 )] 2+ (1) with dioxygen in CH 2 Cl 2 , provides a diiron( iv )-oxo species as a...
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| creator | Sekino, Mio Furutachi, Hideki Tojo, Rina Hishi, Ayumi Kajikawa, Hanako Suzuki, Takatoshi Suzuki, Kaito Fujinami, Shuhei Akine, Shigehisa Sakata, Yoko Ohta, Takehiro Hayami, Shinya Suzuki, Masatatsu |
| description | A (μ-peroxo)diiron(
iii
) complex [Fe
2
(L
Ph
4
)(O
2
)(Ph
3
CCO
2
)]
2+
(1-O
2
) with a dinucleating ligand (L
Ph
4
), generated from the reaction of a carboxylate bridged diiron(
ii
) complex [Fe
2
(L
Ph
4
)(Ph
3
CCO
2
)]
2+
(1) with dioxygen in CH
2
Cl
2
, provides a diiron(
iv
)-oxo species as an active oxidant which is involved in either aromatic ligand hydroxylation or benzyl alcohol oxidation.
A diiron(
iv
)-oxo species (
1
-oxo) is an essential intermediate in the oxidation reaction initiated by
1
-O
2
. |
| doi_str_mv | 10.1039/c7cc04382a |
| format | article |
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iii
) complex [Fe
2
(L
Ph
4
)(O
2
)(Ph
3
CCO
2
)]
2+
(1-O
2
) with a dinucleating ligand (L
Ph
4
), generated from the reaction of a carboxylate bridged diiron(
ii
) complex [Fe
2
(L
Ph
4
)(Ph
3
CCO
2
)]
2+
(1) with dioxygen in CH
2
Cl
2
, provides a diiron(
iv
)-oxo species as an active oxidant which is involved in either aromatic ligand hydroxylation or benzyl alcohol oxidation.
A diiron(
iv
)-oxo species (
1
-oxo) is an essential intermediate in the oxidation reaction initiated by
1
-O
2
.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c7cc04382a</identifier><language>eng</language><creationdate>2017-08</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Sekino, Mio</creatorcontrib><creatorcontrib>Furutachi, Hideki</creatorcontrib><creatorcontrib>Tojo, Rina</creatorcontrib><creatorcontrib>Hishi, Ayumi</creatorcontrib><creatorcontrib>Kajikawa, Hanako</creatorcontrib><creatorcontrib>Suzuki, Takatoshi</creatorcontrib><creatorcontrib>Suzuki, Kaito</creatorcontrib><creatorcontrib>Fujinami, Shuhei</creatorcontrib><creatorcontrib>Akine, Shigehisa</creatorcontrib><creatorcontrib>Sakata, Yoko</creatorcontrib><creatorcontrib>Ohta, Takehiro</creatorcontrib><creatorcontrib>Hayami, Shinya</creatorcontrib><creatorcontrib>Suzuki, Masatatsu</creatorcontrib><title>New mechanistic insights into intramolecular aromatic ligand hydroxylation and benzyl alcohol oxidation initiated by the well-defined (μ-peroxo)diiron(iii) complexElectronic supplementary information (ESI) available: Experimental details of synthesis, and structural, spectroscopic, kinetic, and DFT data. CCDC 1554479. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7cc04382a</title><description>A (μ-peroxo)diiron(
iii
) complex [Fe
2
(L
Ph
4
)(O
2
)(Ph
3
CCO
2
)]
2+
(1-O
2
) with a dinucleating ligand (L
Ph
4
), generated from the reaction of a carboxylate bridged diiron(
ii
) complex [Fe
2
(L
Ph
4
)(Ph
3
CCO
2
)]
2+
(1) with dioxygen in CH
2
Cl
2
, provides a diiron(
iv
)-oxo species as an active oxidant which is involved in either aromatic ligand hydroxylation or benzyl alcohol oxidation.
A diiron(
iv
)-oxo species (
1
-oxo) is an essential intermediate in the oxidation reaction initiated by
1
-O
2
.</description><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFUbFu2zAQVYoWaJJ26R7gutmA5VqRVNtZZRv10g7JkM24UJR1DUUKPDqx8jX5kHxDv6knu0CGAi0H8vDu8b13ZBR9SibjZJLOv6ipUpMsnV3im-g0Sb9mcZ7Nbt_2dT6Pp2mWv4_OmH9OZCX57PTk-bt-hEarGi1xIAVkmbZ1YCmC6zePjTNa7Qx6QO8a7FmGtmhLqLvSu31nBHMWeuRO26fOABrlamfA7ak8NslSIAxaKB2EWsOjNiYudUVWsMGvl7jVouWGJZF3dkBEQ1CuaY3eL8U_CCjGvGsFabQN6DsRrZxvjgaD5fV6CPiAZPDO6CtY7kWRDlQDpQ7SYHAVcGfFn4lHh8Qc_E6FnUczAm4PRqxcS2oE95It9EXPW6xuQGbBMRTFooAkz7NsOh_DynkQ6wNH-Y7Fzbitx7aWuP0FSQnFegXCc2LsQb-Oc4wPrDUsfqyv4O9__BC9q9Cw_vjnPI8uVsub4lvsWW1amU_eYfNKT8-jz__qb9qySv-n8RsW7sQY</recordid><startdate>20170803</startdate><enddate>20170803</enddate><creator>Sekino, Mio</creator><creator>Furutachi, Hideki</creator><creator>Tojo, Rina</creator><creator>Hishi, Ayumi</creator><creator>Kajikawa, Hanako</creator><creator>Suzuki, Takatoshi</creator><creator>Suzuki, Kaito</creator><creator>Fujinami, Shuhei</creator><creator>Akine, Shigehisa</creator><creator>Sakata, Yoko</creator><creator>Ohta, Takehiro</creator><creator>Hayami, Shinya</creator><creator>Suzuki, Masatatsu</creator><scope/></search><sort><creationdate>20170803</creationdate><title>New mechanistic insights into intramolecular aromatic ligand hydroxylation and benzyl alcohol oxidation initiated by the well-defined (μ-peroxo)diiron(iii) complexElectronic supplementary information (ESI) available: Experimental details of synthesis, and structural, spectroscopic, kinetic, and DFT data. CCDC 1554479. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7cc04382a</title><author>Sekino, Mio ; Furutachi, Hideki ; Tojo, Rina ; Hishi, Ayumi ; Kajikawa, Hanako ; Suzuki, Takatoshi ; Suzuki, Kaito ; Fujinami, Shuhei ; Akine, Shigehisa ; Sakata, Yoko ; Ohta, Takehiro ; Hayami, Shinya ; Suzuki, Masatatsu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c7cc04382a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sekino, Mio</creatorcontrib><creatorcontrib>Furutachi, Hideki</creatorcontrib><creatorcontrib>Tojo, Rina</creatorcontrib><creatorcontrib>Hishi, Ayumi</creatorcontrib><creatorcontrib>Kajikawa, Hanako</creatorcontrib><creatorcontrib>Suzuki, Takatoshi</creatorcontrib><creatorcontrib>Suzuki, Kaito</creatorcontrib><creatorcontrib>Fujinami, Shuhei</creatorcontrib><creatorcontrib>Akine, Shigehisa</creatorcontrib><creatorcontrib>Sakata, Yoko</creatorcontrib><creatorcontrib>Ohta, Takehiro</creatorcontrib><creatorcontrib>Hayami, Shinya</creatorcontrib><creatorcontrib>Suzuki, Masatatsu</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sekino, Mio</au><au>Furutachi, Hideki</au><au>Tojo, Rina</au><au>Hishi, Ayumi</au><au>Kajikawa, Hanako</au><au>Suzuki, Takatoshi</au><au>Suzuki, Kaito</au><au>Fujinami, Shuhei</au><au>Akine, Shigehisa</au><au>Sakata, Yoko</au><au>Ohta, Takehiro</au><au>Hayami, Shinya</au><au>Suzuki, Masatatsu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>New mechanistic insights into intramolecular aromatic ligand hydroxylation and benzyl alcohol oxidation initiated by the well-defined (μ-peroxo)diiron(iii) complexElectronic supplementary information (ESI) available: Experimental details of synthesis, and structural, spectroscopic, kinetic, and DFT data. CCDC 1554479. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7cc04382a</atitle><date>2017-08-03</date><risdate>2017</risdate><volume>53</volume><issue>63</issue><spage>8838</spage><epage>8841</epage><pages>8838-8841</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>A (μ-peroxo)diiron(
iii
) complex [Fe
2
(L
Ph
4
)(O
2
)(Ph
3
CCO
2
)]
2+
(1-O
2
) with a dinucleating ligand (L
Ph
4
), generated from the reaction of a carboxylate bridged diiron(
ii
) complex [Fe
2
(L
Ph
4
)(Ph
3
CCO
2
)]
2+
(1) with dioxygen in CH
2
Cl
2
, provides a diiron(
iv
)-oxo species as an active oxidant which is involved in either aromatic ligand hydroxylation or benzyl alcohol oxidation.
A diiron(
iv
)-oxo species (
1
-oxo) is an essential intermediate in the oxidation reaction initiated by
1
-O
2
.</abstract><doi>10.1039/c7cc04382a</doi><tpages>4</tpages></addata></record> |
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| source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
| title | New mechanistic insights into intramolecular aromatic ligand hydroxylation and benzyl alcohol oxidation initiated by the well-defined (μ-peroxo)diiron(iii) complexElectronic supplementary information (ESI) available: Experimental details of synthesis, and structural, spectroscopic, kinetic, and DFT data. CCDC 1554479. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7cc04382a |
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