Cobalt(ii)-catalyzed chelation-assisted C-H iodination of aromatic amides with I2Electronic supplementary information (ESI) available. See DOI: 10.1039/c7cc08457a

The cobalt-catalyzed chelation-assisted iodination of aromatic amides using molecular I 2 as an iodinating reagent is reported. 8-Amino-5-chloroquinoline functions as an efficient directing group. This mild and air stable catalytic system shows a wide functional group tolerance and improved syntheti...

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Bibliographic Details
Main Authors: Kommagalla, Yadagiri, Yamazaki, Ken, Yamaguchi, Takuma, Chatani, Naoto
Format: Article
Language:English
Online Access:Get full text
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Summary:The cobalt-catalyzed chelation-assisted iodination of aromatic amides using molecular I 2 as an iodinating reagent is reported. 8-Amino-5-chloroquinoline functions as an efficient directing group. This mild and air stable catalytic system shows a wide functional group tolerance and improved synthetic accessibility. An air stable and inexpensive cobalt-metal, mild and efficient catalytic system.
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc08457a