Redox effects of low-spin Ru(ii/iii) on slow magnetic relaxation of Ru-Mn(iii) 1D cyanide-bridged complexesElectronic supplementary information (ESI) available: Experimental details, crystallographic data, spectrogram, additional magnetic data, and crystallographic information files (CIF). CCDC 1518135, 1518136. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7dt01218g

A new one-dimensional cyanide-bridged complex [Mn III (salphen)Ru II (DMAP) 4 (CN) 2 ](PF 6 ) ( 1 ) and its oxidized derivative [Mn III (salphen)Ru III (DMAP) 4 (CN) 2 ](PF 6 ) 2 ( 2 ) have been synthesized and fully characterized. Magnetic measurements showed that 1 shows simple paramagnetism but 2...

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Main Authors: Zhu, Xiaoquan, Su, Shaodong, Cao, Wenhai, Wen, Yuehong, Hu, Shengmin, Wu, Xintao, Sheng, Tianlu
Format: Article
Language:English
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Summary:A new one-dimensional cyanide-bridged complex [Mn III (salphen)Ru II (DMAP) 4 (CN) 2 ](PF 6 ) ( 1 ) and its oxidized derivative [Mn III (salphen)Ru III (DMAP) 4 (CN) 2 ](PF 6 ) 2 ( 2 ) have been synthesized and fully characterized. Magnetic measurements showed that 1 shows simple paramagnetism but 2 shows intrachain ferromagnetic interaction with slow magnetic relaxation. Redox active Ru-based cyanide bridges Mn( iii ) fragments with different oxidation states and forms two new 1D compounds, of which one shows simple paramagnetism and another shows slow magnetic relaxation.
ISSN:1477-9226
1477-9234
DOI:10.1039/c7dt01218g