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Water oxidation by simple manganese salts in the presence of cerium(iv) ammonium nitrate: towards a complete pictureElectronic supplementary information (ESI) available. See DOI: 10.1039/c7dt04143h
For the first time, using scanning electron microscopy, transmission electron microscopy, X-ray absorption near edge structure and extended X-ray absorption fine structure X-ray diffraction, it is showed that MnCO 3 , MnWO 4 , Mn 3 (PO 4 ) 2 ·3H 2 O, MnS and Mn(VO 3 ) 2 · x H 2 O under the water-oxi...
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| container_issue | 5 |
| container_start_page | 1557 |
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| container_volume | 47 |
| creator | Heidari, Sima Najafpour, Mohammad Mahdi Ho y ska, Ma gorzata Singh, Jitendra Pal Chae, Keun Hwa Khatamian, Masoumeh |
| description | For the first time, using scanning electron microscopy, transmission electron microscopy, X-ray absorption near edge structure and extended X-ray absorption fine structure X-ray diffraction, it is showed that MnCO
3
, MnWO
4
, Mn
3
(PO
4
)
2
·3H
2
O, MnS and Mn(VO
3
)
2
·
x
H
2
O under the water-oxidation conditions and in the presence of cerium(
iv
) ammonium nitrate, are converted to Mn oxide without a high-range order. A mechanism is proposed for such conversion and as Mn oxide is an efficient water-oxidizing catalyst, it is thus a candidate as a contributor to the observed catalytic activity.
For the first time, using some methods, we showed that under the water-oxidation conditions and in the presence of cerium(
iv
) ammonium nitrate, some manganese salts are converted to Mn oxide. |
| doi_str_mv | 10.1039/c7dt04143h |
| format | article |
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3
, MnWO
4
, Mn
3
(PO
4
)
2
·3H
2
O, MnS and Mn(VO
3
)
2
·
x
H
2
O under the water-oxidation conditions and in the presence of cerium(
iv
) ammonium nitrate, are converted to Mn oxide without a high-range order. A mechanism is proposed for such conversion and as Mn oxide is an efficient water-oxidizing catalyst, it is thus a candidate as a contributor to the observed catalytic activity.
For the first time, using some methods, we showed that under the water-oxidation conditions and in the presence of cerium(
iv
) ammonium nitrate, some manganese salts are converted to Mn oxide.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c7dt04143h</identifier><language>eng</language><creationdate>2018-01</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Heidari, Sima</creatorcontrib><creatorcontrib>Najafpour, Mohammad Mahdi</creatorcontrib><creatorcontrib>Ho y ska, Ma gorzata</creatorcontrib><creatorcontrib>Singh, Jitendra Pal</creatorcontrib><creatorcontrib>Chae, Keun Hwa</creatorcontrib><creatorcontrib>Khatamian, Masoumeh</creatorcontrib><title>Water oxidation by simple manganese salts in the presence of cerium(iv) ammonium nitrate: towards a complete pictureElectronic supplementary information (ESI) available. See DOI: 10.1039/c7dt04143h</title><description>For the first time, using scanning electron microscopy, transmission electron microscopy, X-ray absorption near edge structure and extended X-ray absorption fine structure X-ray diffraction, it is showed that MnCO
3
, MnWO
4
, Mn
3
(PO
4
)
2
·3H
2
O, MnS and Mn(VO
3
)
2
·
x
H
2
O under the water-oxidation conditions and in the presence of cerium(
iv
) ammonium nitrate, are converted to Mn oxide without a high-range order. A mechanism is proposed for such conversion and as Mn oxide is an efficient water-oxidizing catalyst, it is thus a candidate as a contributor to the observed catalytic activity.
For the first time, using some methods, we showed that under the water-oxidation conditions and in the presence of cerium(
iv
) ammonium nitrate, some manganese salts are converted to Mn oxide.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFj7tOA0EMRUcIJEKgoUcyXSgSZh8QJS0sIhVFkChXzqyXDJrHasYbyAfyXxkEggIJKj_u9bEtxGkmJ5ksZpdq2rAss7JY74lBVk6n41lelPvfeX59KI5ifJEyz-VVPhDvT8gUwL_pBll7B6stRG07Q2DRPaOjSBDRcATtgNcEXUgtpwh8C4qC7u1Iby4ArfUuFeA0h8ScA_tXDE0EBOU_gJxmteI-UGVIcUh2BbHvkmTJMYZtWtH6YD8PGVXLRcJuUBtcGZrAkghuHxZz-P3ssTho0UQ6-YpDcXZXPd7cj0NUdRe0TfD6x14Mxflfet01bfEfYweQZnUW</recordid><startdate>20180130</startdate><enddate>20180130</enddate><creator>Heidari, Sima</creator><creator>Najafpour, Mohammad Mahdi</creator><creator>Ho y ska, Ma gorzata</creator><creator>Singh, Jitendra Pal</creator><creator>Chae, Keun Hwa</creator><creator>Khatamian, Masoumeh</creator><scope/></search><sort><creationdate>20180130</creationdate><title>Water oxidation by simple manganese salts in the presence of cerium(iv) ammonium nitrate: towards a complete pictureElectronic supplementary information (ESI) available. See DOI: 10.1039/c7dt04143h</title><author>Heidari, Sima ; Najafpour, Mohammad Mahdi ; Ho y ska, Ma gorzata ; Singh, Jitendra Pal ; Chae, Keun Hwa ; Khatamian, Masoumeh</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c7dt04143h3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Heidari, Sima</creatorcontrib><creatorcontrib>Najafpour, Mohammad Mahdi</creatorcontrib><creatorcontrib>Ho y ska, Ma gorzata</creatorcontrib><creatorcontrib>Singh, Jitendra Pal</creatorcontrib><creatorcontrib>Chae, Keun Hwa</creatorcontrib><creatorcontrib>Khatamian, Masoumeh</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Heidari, Sima</au><au>Najafpour, Mohammad Mahdi</au><au>Ho y ska, Ma gorzata</au><au>Singh, Jitendra Pal</au><au>Chae, Keun Hwa</au><au>Khatamian, Masoumeh</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Water oxidation by simple manganese salts in the presence of cerium(iv) ammonium nitrate: towards a complete pictureElectronic supplementary information (ESI) available. See DOI: 10.1039/c7dt04143h</atitle><date>2018-01-30</date><risdate>2018</risdate><volume>47</volume><issue>5</issue><spage>1557</spage><epage>1565</epage><pages>1557-1565</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>For the first time, using scanning electron microscopy, transmission electron microscopy, X-ray absorption near edge structure and extended X-ray absorption fine structure X-ray diffraction, it is showed that MnCO
3
, MnWO
4
, Mn
3
(PO
4
)
2
·3H
2
O, MnS and Mn(VO
3
)
2
·
x
H
2
O under the water-oxidation conditions and in the presence of cerium(
iv
) ammonium nitrate, are converted to Mn oxide without a high-range order. A mechanism is proposed for such conversion and as Mn oxide is an efficient water-oxidizing catalyst, it is thus a candidate as a contributor to the observed catalytic activity.
For the first time, using some methods, we showed that under the water-oxidation conditions and in the presence of cerium(
iv
) ammonium nitrate, some manganese salts are converted to Mn oxide.</abstract><doi>10.1039/c7dt04143h</doi><tpages>9</tpages></addata></record> |
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| source | Royal Society of Chemistry |
| title | Water oxidation by simple manganese salts in the presence of cerium(iv) ammonium nitrate: towards a complete pictureElectronic supplementary information (ESI) available. See DOI: 10.1039/c7dt04143h |
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