An unprecedented 3D architecture based on a Nb/W mixed-addendum polyoxometalate and lanthanide-organic complex: synthesis, crystal structure and propertiesElectronic supplementary information (ESI) available: X-ray crystallographic file in CIF format; synthesis discussion; structural figures; and additional properties and characterization. CCDC 1544073. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7nj02011b

For the first time, an unprecedented 3D framework based on lanthanide-containing Nb/W mixed-addendum polyoxometalate [H 3 La 8 (H 2 O) 32 (C 6 H 5 NO 2 ) 6 ][SiW 9 Nb 3 O 40 ] 3 ·8H 2 O ( 1 ) has been obtained by utilizing the steam-assisted conversion method. Meanwhile, the stability, electrochemic...

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Main Authors: Yang, Mei-Si, Chen, Wei-Chao, Qin, Chao, Yao, Wei, Yin, Ying-Xue, Su, Zhong-Min
Format: Article
Language:English
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Summary:For the first time, an unprecedented 3D framework based on lanthanide-containing Nb/W mixed-addendum polyoxometalate [H 3 La 8 (H 2 O) 32 (C 6 H 5 NO 2 ) 6 ][SiW 9 Nb 3 O 40 ] 3 ·8H 2 O ( 1 ) has been obtained by utilizing the steam-assisted conversion method. Meanwhile, the stability, electrochemical behavior, and photoluminescence properties of 1 have also been discussed. For the first time, a 3D framework based on lanthanide-containing Nb/W mixed-addendum polyoxometalate has been obtained by utilizing the steam-assisted conversion method.
ISSN:1144-0546
1369-9261
DOI:10.1039/c7nj02011b