Palladium-polymer nanoreactors for the aqueous asymmetric synthesis of therapeutic flavonoidsElectronic supplementary information (ESI) available: Detailed experimental procedures for the synthesis of procedures, NMR, SEC, UV-Vis, LS, TEM and HPLC characterization data and table of catalysis control experiments. See DOI: 10.1039/c7py02050c

Polymeric core-shell micelles incorporating a chiral palladium pyridinooxazoline catalyst are presented as nanoreactors for the aqueous asymmetric synthesis of flavanones, a class of flavonoids with therapeutic properties. Use of the nanoreactor was found to increase catalyst activity, enabling cata...

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Main Authors: Lestini, E, Blackman, L. D, Zammit, C. M, Chen, T, Williams, R. J, Inam, M, Couturaud, B, O'Reilly, R. K
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Summary:Polymeric core-shell micelles incorporating a chiral palladium pyridinooxazoline catalyst are presented as nanoreactors for the aqueous asymmetric synthesis of flavanones, a class of flavonoids with therapeutic properties. Use of the nanoreactor was found to increase catalyst activity, enabling catalysis at room temperature, with low palladium loadings and without any additives. Polymeric core-shell micelles incorporating a chiral palladium pyridinooxazoline catalyst are presented as nanoreactors for the aqueous asymmetric synthesis of flavanones, a class of flavonoids, with therapeutic properties.
ISSN:1759-9954
1759-9962
DOI:10.1039/c7py02050c