Directed ortho C-H borylation catalyzed using CpRh(iii)-NHC complexesElectronic supplementary information (ESI) available: NMR spectra. CCDC 1405507 and 1818181. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8cc03144d

Cp*Rh(NHC) complexes with bulky chiral bidentate NHC-carboxylate ligands were efficiently synthesized and fully characterized including solid-state structures. These unprecedented rhodium( iii ) complexes demonstrated high selectivity in pyridine-directed ortho -C-H borylation of arenes under mild c...

Full description

Saved in:
Bibliographic Details
Main Authors: Thongpaen, Jompol, Schmid, Thibault, Toupet, Loic, Dorcet, Vincent, Mauduit, Marc, Baslé, Olivier
Format: Article
Language:English
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Cp*Rh(NHC) complexes with bulky chiral bidentate NHC-carboxylate ligands were efficiently synthesized and fully characterized including solid-state structures. These unprecedented rhodium( iii ) complexes demonstrated high selectivity in pyridine-directed ortho -C-H borylation of arenes under mild conditions. Cp*Rh(NHC) complexes with bulky chiral bidentate NHC-carboxylate ligands demonstrated high selectivity in the pyridine-directed C-H borylation of arenes under mild conditions.
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc03144d