Topology meets MOF chemistry for pore-aperture fine tuning: -MOF platform for energy-efficient separations adsorption kinetics or molecular sieving

Herein we demonstrate how the combined use of the molecular building block (MBB) approach and reticular chemistry allows the fabrication of a highly stable, ultra-microporous metal-organic framework (MOF) that is an efficient sorbent for the challenging separation of propane/propylene. The MBB appro...

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Published in:Chemical communications (Cambridge, England) England), 2018-06, Vol.54 (49), p.644-647
Main Authors: Xue, Dong-Xu, Cadiau, Amandine, Weseli ski, ukasz J, Jiang, Hao, Bhatt, Prashant M, Shkurenko, Aleksander, Wojtas, Lukasz, Zhijie, Chen, Belmabkhout, Youssef, Adil, Karim, Eddaoudi, Mohamed
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Summary:Herein we demonstrate how the combined use of the molecular building block (MBB) approach and reticular chemistry allows the fabrication of a highly stable, ultra-microporous metal-organic framework (MOF) that is an efficient sorbent for the challenging separation of propane/propylene. The MBB approach permitted the construction of a highly stable ftw -MOF for intricate separations.
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc03841d