Topology meets MOF chemistry for pore-aperture fine tuning: -MOF platform for energy-efficient separations adsorption kinetics or molecular sieving

Herein we demonstrate how the combined use of the molecular building block (MBB) approach and reticular chemistry allows the fabrication of a highly stable, ultra-microporous metal-organic framework (MOF) that is an efficient sorbent for the challenging separation of propane/propylene. The MBB appro...

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Published in:Chemical communications (Cambridge, England) England), 2018-06, Vol.54 (49), p.644-647
Main Authors: Xue, Dong-Xu, Cadiau, Amandine, Weseli ski, ukasz J, Jiang, Hao, Bhatt, Prashant M, Shkurenko, Aleksander, Wojtas, Lukasz, Zhijie, Chen, Belmabkhout, Youssef, Adil, Karim, Eddaoudi, Mohamed
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container_issue 49
container_start_page 644
container_title Chemical communications (Cambridge, England)
container_volume 54
creator Xue, Dong-Xu
Cadiau, Amandine
Weseli ski, ukasz J
Jiang, Hao
Bhatt, Prashant M
Shkurenko, Aleksander
Wojtas, Lukasz
Zhijie, Chen
Belmabkhout, Youssef
Adil, Karim
Eddaoudi, Mohamed
description Herein we demonstrate how the combined use of the molecular building block (MBB) approach and reticular chemistry allows the fabrication of a highly stable, ultra-microporous metal-organic framework (MOF) that is an efficient sorbent for the challenging separation of propane/propylene. The MBB approach permitted the construction of a highly stable ftw -MOF for intricate separations.
doi_str_mv 10.1039/c8cc03841d
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title Topology meets MOF chemistry for pore-aperture fine tuning: -MOF platform for energy-efficient separations adsorption kinetics or molecular sieving
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