Kitchen grinder: a tool for the synthesis of metal-organic frameworks towards size selective dye adsorption

In this report, we present a simple, swift mechanochemical synthesis of metal-organic frameworks (MOFs) using a kitchen grinder. By adopting this tool, we could synthesize ZIF-8, CuBTC, and MIL-100(Fe) in multi gram-scale and successfully employ MIL-100(Fe)-KG for the efficient ( ca. 98%) removal of...

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Published in:CrystEngComm 2018, Vol.2 (18), p.2486-249
Main Authors: Samal, Mahalaxmi, Panda, Jagannath, Biswal, Bishnu P, Sahu, Rojalin
Format: Article
Language:English
Subjects:
Adsorption
Dyes
Methylene blue
Synthesis
Wastewater treatment
Water treatment
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description In this report, we present a simple, swift mechanochemical synthesis of metal-organic frameworks (MOFs) using a kitchen grinder. By adopting this tool, we could synthesize ZIF-8, CuBTC, and MIL-100(Fe) in multi gram-scale and successfully employ MIL-100(Fe)-KG for the efficient ( ca. 98%) removal of an organic dye (methylene blue) from aqueous solution. In particular, we demonstrated the significance of pore aperture for effective dye adsorption by comparing the adsorption behaviours of ZIF-8-KG and MIL-100(Fe)-KG. We believe that this approach could be of economic interest towards the green synthesis of porous adsorbents for waste-water treatment. A simple, swift mechanochemical approach for MOF synthesis using kitchen grinder has been developed for size selective dye adsorption.
doi_str_mv 10.1039/c8ce00333e
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subjects Adsorption
Dyes
Methylene blue
Synthesis
Wastewater treatment
Water treatment
title Kitchen grinder: a tool for the synthesis of metal-organic frameworks towards size selective dye adsorption
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