Platinum-mediated monohydration of SO

The monohydration of SO 2 has been achieved in solution mediated by a platinum-aquo complex. Benzamidate ligands play a key role along the process, acting as versatile proton shuttles. Finally, the platinum center allows the stabilization of benzimidic acid and a hydrogensulphite anion, the disfavor...

Full description

Saved in:
Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2018-12, Vol.47 (47), p.16846-16849
Main Authors: Gimeno-Prat, Antonio, Cortés-Sanchón, Adrián, Martín, Antonio, Baya, Miguel, Casas, José M
Format: Article
Language:
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The monohydration of SO 2 has been achieved in solution mediated by a platinum-aquo complex. Benzamidate ligands play a key role along the process, acting as versatile proton shuttles. Finally, the platinum center allows the stabilization of benzimidic acid and a hydrogensulphite anion, the disfavored tautomers of benzamide and sulphonate, respectively. The monohydration of SO 2 has been achieved in solution mediated by a platinum-aquo complex.
ISSN:1477-9226
1477-9234
DOI:10.1039/c8dt04169e