Platinum-mediated monohydration of SO

The monohydration of SO 2 has been achieved in solution mediated by a platinum-aquo complex. Benzamidate ligands play a key role along the process, acting as versatile proton shuttles. Finally, the platinum center allows the stabilization of benzimidic acid and a hydrogensulphite anion, the disfavor...

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Published in:Dalton transactions : an international journal of inorganic chemistry 2018-12, Vol.47 (47), p.16846-16849
Main Authors: Gimeno-Prat, Antonio, Cortés-Sanchón, Adrián, Martín, Antonio, Baya, Miguel, Casas, José M
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container_issue 47
container_start_page 16846
container_title Dalton transactions : an international journal of inorganic chemistry
container_volume 47
creator Gimeno-Prat, Antonio
Cortés-Sanchón, Adrián
Martín, Antonio
Baya, Miguel
Casas, José M
description The monohydration of SO 2 has been achieved in solution mediated by a platinum-aquo complex. Benzamidate ligands play a key role along the process, acting as versatile proton shuttles. Finally, the platinum center allows the stabilization of benzimidic acid and a hydrogensulphite anion, the disfavored tautomers of benzamide and sulphonate, respectively. The monohydration of SO 2 has been achieved in solution mediated by a platinum-aquo complex.
doi_str_mv 10.1039/c8dt04169e
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title Platinum-mediated monohydration of SO
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