Enhanced release of palladium and platinum from catalytic converter materials exposed to ammonia and chloride bearing solutions

• Published in: Environmental science--processes & impacts 2019-01, Vol.21 (1), p.133-144
• Main Authors: Aruguete, Deborah M, Murayama, Mitsuhiro, Blakney, Terry, Winkler, Christopher
• Format: Article
• Language: English
• Subjects: Aluminum oxide; Ammonia; Automotive parts; Catalytic converters; Cerium oxides; Chemotherapy; Cisplatin; Combustion products; Coordination compounds; Emission control equipment; Exhaust emissions; Exhaust systems; Exposure; Ligands; Metals; Nanoparticles; Palladium; Platinum; Sodium chloride; Soil water; Transitional aluminas; Zirconia; Zirconium dioxide
• ISSN: 2050-7887; 2050-7895
• DOI: 10.1039/c8em00370j

The environmental levels of platinum group elements (PGEs) are steadily rising, primarily due to exhaust emissions of vehicle catalytic converter (VCC) materials containing solid PGEs. Once these VCC materials reach soil and water, the PGEs may be transported in the form of nanoparticles (dimensions 1-100 nm) or they may be mobilized by forming coordination complexes with ligands in the environment. Chloride (Cl − ) and ammonia (NH 3 ) are two ligands of particular concern due to their ubiquity as well as their potential to form the chemotherapy drug cisplatin (Pt(NH 3 ) 2 Cl 2 ) or other potentially bioactive complexes. This initial study examines the release of Pd and Pt into solutions exposed to VCC materials at pH 8 and 25 °C, using elemental analysis of metal content in post-exposure extracts. The solutions had total ammonia nitrogen concentrations (TAN, [NH 4 + ] + [NH 3 ]) of 0 μM, 5.56 μM, 55.6 μM and 1.13 × 10 5 μM (0 ppm, 0.1 ppm, 1 ppm, and 2147 ppm). The former three represent background environmental levels had a minimal effect on release. However, when combined with 1.13 × 10 5 μM Cl − (4000 ppm Cl − ), 55.6 μM TAN induced a marked increase in metal release (∼41× for Pd). High TAN solutions induced more Pd and Pt release than equimolar NaCl solutions. Materials characterization revealed that ∼4 nm palladium-containing nanoparticles were present, spatially associated with nanoparticles of γ-Al 2 O 3 ; ceria-zirconia nanoparticles were also present but did not have any metal associated with them. Platinum-containing nanoparticles were not observed. Results suggest that systems with elevated salinity and trace ammonia could induce release of palladium/platinum from emitted vehicle catalytic converter (VCC) materials; electron microscopy suggests the presence of non-metallic palladium in VCCs.