Mono-DMSO ligated cobalt nitrophenylcorroles: electrochemical and spectral characterizationElectronic supplementary information (ESI) available. See DOI: 10.1039/c8nj00300a

Four mono-DMSO ligated cobalt corroles with one or three meso -nitrophenyl substituents on the macrocycle were synthesized and investigated as to their electrochemical and spectroscopic properties in CH 2 Cl 2 and DMSO. Comparisons are made between redox reactions of the five-coordinate DMSO adducts...

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Main Authors: Jiang, X, Shan, W, Desbois, N, Quesneau, V, Brandès, S, Caemelbecke, E. Van, Osterloh, W. R, Blondeau-Patissier, V, Gros, C. P, Kadish, K. M
Format: Article
Language:English
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Summary:Four mono-DMSO ligated cobalt corroles with one or three meso -nitrophenyl substituents on the macrocycle were synthesized and investigated as to their electrochemical and spectroscopic properties in CH 2 Cl 2 and DMSO. Comparisons are made between redox reactions of the five-coordinate DMSO adducts in the current study and earlier examined five- and six-coordinate cobalt corroles with pyridine axial ligands which were characterized in a variety of nonaqueous electrochemical solvents. The binding of carbon monoxide (CO) is also investigated. Four mono-DMSO ligated cobalt corroles with one or three meso -nitrophenyl substituents on the macrocycle were synthesized and investigated as to their electrochemical and spectroscopic properties in CH 2 Cl 2 and DMSO.
ISSN:1144-0546
1369-9261
DOI:10.1039/c8nj00300a