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Homogeneity and tolerance to heat of monolayer MoS on SiO and h-BN

We investigated the homogeneity and tolerance to heat of monolayer MoS 2 using photoluminescence (PL) spectroscopy. For MoS 2 on SiO 2 , the PL spectra of the basal plane differ from those of the edge, but MoS 2 on hexagonal boron nitride (h-BN) was electron-depleted with a homogeneous PL spectra ov...

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Published in:RSC advances 2018-04, Vol.8 (23), p.129-1296
Main Authors: Kim, Ho-Jong, Kim, Daehee, Jung, Suyong, Bae, Myung-Ho, Yi, Sam Nyung, Watanabe, Kenji, Taniguchi, Takashi, Chang, Soo Kyung, Ha, Dong Han
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container_end_page 1296
container_issue 23
container_start_page 129
container_title RSC advances
container_volume 8
creator Kim, Ho-Jong
Kim, Daehee
Jung, Suyong
Bae, Myung-Ho
Yi, Sam Nyung
Watanabe, Kenji
Taniguchi, Takashi
Chang, Soo Kyung
Ha, Dong Han
description We investigated the homogeneity and tolerance to heat of monolayer MoS 2 using photoluminescence (PL) spectroscopy. For MoS 2 on SiO 2 , the PL spectra of the basal plane differ from those of the edge, but MoS 2 on hexagonal boron nitride (h-BN) was electron-depleted with a homogeneous PL spectra over the entire area. Annealing at 450 °C rendered MoS 2 on SiO 2 homogeneously electron-depleted over the entire area by creating numerous defects; moreover, annealing at 550 °C and subsequent laser irradiation on the MoS 2 monolayer caused a loss of its inherent crystal structure. On the other hand, monolayer MoS 2 on h-BN was preserved up to 550 °C with its PL spectra not much changed compared with MoS 2 on SiO 2 . We performed an experiment to qualitatively compare the binding energies between various layers, and discuss the tolerance of monolayer MoS 2 to heat on the basis of interlayer/interfacial binding energy. We investigated the homogeneity and tolerance to heat of monolayer MoS 2 using photoluminescence (PL) spectroscopy.
doi_str_mv 10.1039/c8ra01849a
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title Homogeneity and tolerance to heat of monolayer MoS on SiO and h-BN
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