Enhanced redox activity of a hollow conjugated microporous polymer through the generation of carbonyl groups by carbonylative Sonogashira couplingElectronic supplementary information (ESI) available: Experimental procedures, additional cyclic voltammograms and TEM images of H-CMP and H-CMP-BPPB. See DOI: 10.1039/c8ta01379a

Redox active 1,4-bis(3-phenylpropynoyl)benzene moieties were incorporated into a hollow conjugated microporous polymer via carbonylative Sonogashira coupling of 1,3,5-triethynylbenzene with 1,4-diiodobenzene in the presence of carbon monoxide. The resultant redox active material showed enhanced ener...

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Main Authors: Choi, Jaewon, Ko, Ju Hong, Kang, Chang Wan, Lee, Sang Moon, Kim, Hae Jin, Ko, Yoon-Joo, Yang, MinHo, Son, Seung Uk
Format: Article
Language:English
Online Access:Get full text
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Summary:Redox active 1,4-bis(3-phenylpropynoyl)benzene moieties were incorporated into a hollow conjugated microporous polymer via carbonylative Sonogashira coupling of 1,3,5-triethynylbenzene with 1,4-diiodobenzene in the presence of carbon monoxide. The resultant redox active material showed enhanced energy storage performance for pseudocapacitors. The carbonylative Sonogashira coupling reaction enhanced the redox activity of a hollow conjugated microporous polymer.
ISSN:2050-7488
2050-7496
DOI:10.1039/c8ta01379a