A convenient access to allylic triflones with allenes and triflyl chloride in the presence of (EtO)P(O)H

A simple method for the preparation of allylic triflones from allenes and triflyl chloride in the presence of (EtO) 2 P(O)H has been developed. The features of this reaction are catalyst-free and simple starting substrates. This method tolerates diverse functional groups and substituted allylic trif...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2019-06, Vol.55 (51), p.7343-7345
Main Authors: Ni, Jixiang, Jiang, Yong, An, Zhenyu, Lan, Jingfeng, Yan, Rulong
Format: Article
Language:English
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Summary:A simple method for the preparation of allylic triflones from allenes and triflyl chloride in the presence of (EtO) 2 P(O)H has been developed. The features of this reaction are catalyst-free and simple starting substrates. This method tolerates diverse functional groups and substituted allylic triflones are obtained in moderate to good yields. A simple method for the preparation of allylic triflones from allenes and triflyl chloride in the presence of (EtO) 2 P(O)H has been developed.
ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc03096d