Graphene-aramid nanocomposite fibres superacid co-processing

The development of graphene-polymer nanocomposite materials has been hindered by issues such as poor colloidal stability of graphene in liquid media, weak interactions between graphene and the host polymers as well as the lack of scalable and economical graphene synthesis routes. Chlorosulfonic acid...

Full description

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2019-09, Vol.55 (78), p.1173-1176
Main Authors: Roberts, Aled D, Kelly, Paul, Bain, Jennifer, Morrison, John J, Wimpenny, Ian, Barrow, Mike, Woodward, Robert T, Gresil, Matthieu, Blanford, Christopher, Hay, Sam, Blaker, Jonny J, Yeates, Steve G, Scrutton, Nigel S
Format: Article
Language:
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page 1176
container_issue 78
container_start_page 1173
container_title Chemical communications (Cambridge, England)
container_volume 55
creator Roberts, Aled D
Kelly, Paul
Bain, Jennifer
Morrison, John J
Wimpenny, Ian
Barrow, Mike
Woodward, Robert T
Gresil, Matthieu
Blanford, Christopher
Hay, Sam
Blaker, Jonny J
Yeates, Steve G
Scrutton, Nigel S
description The development of graphene-polymer nanocomposite materials has been hindered by issues such as poor colloidal stability of graphene in liquid media, weak interactions between graphene and the host polymers as well as the lack of scalable and economical graphene synthesis routes. Chlorosulfonic acid (CSA) can spontaneously disperse graphene without the need for mechanical agitation, chemical functionalisation or surfactant stabilisation, 1 however is incompatible with most polymers and organic materials. Here, we demonstrate how poly( p -phenylene terephthalamide) (PPTA) - the polymer which constitutes Kevlar - can be co-processed with graphene in CSA and wet-spun into nanocomposite fibres with minimal aggregation of graphene. Chlorosulfonic acid, an effective graphene dispersant, can be employed to produce graphene-aramid composite fibres.
doi_str_mv 10.1039/c9cc04548a
format article
fullrecord <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_c9cc04548a</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>c9cc04548a</sourcerecordid><originalsourceid>FETCH-rsc_primary_c9cc04548a3</originalsourceid><addsrcrecordid>eNqFjr0KwjAURoMoWH8Wd6EvEE1Ioi24iT8P4OBWrjHViE3CvTr49lYQHP2Wc-AsH2MTKWZSqHJuS2uFNrqADsukWmje-rH7cVPypdKmzwZEN9FOmiJjqx1CurrgOCA0_pwHCNHGJkXyD5fX_oSOcnomh2DbbCNPGK0j8uEyYr0a7uTGXw7ZdLs5rPccyVYJfQP4qn6X1L_-BiRbOkU</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Graphene-aramid nanocomposite fibres superacid co-processing</title><source>Royal Society of Chemistry</source><creator>Roberts, Aled D ; Kelly, Paul ; Bain, Jennifer ; Morrison, John J ; Wimpenny, Ian ; Barrow, Mike ; Woodward, Robert T ; Gresil, Matthieu ; Blanford, Christopher ; Hay, Sam ; Blaker, Jonny J ; Yeates, Steve G ; Scrutton, Nigel S</creator><creatorcontrib>Roberts, Aled D ; Kelly, Paul ; Bain, Jennifer ; Morrison, John J ; Wimpenny, Ian ; Barrow, Mike ; Woodward, Robert T ; Gresil, Matthieu ; Blanford, Christopher ; Hay, Sam ; Blaker, Jonny J ; Yeates, Steve G ; Scrutton, Nigel S</creatorcontrib><description>The development of graphene-polymer nanocomposite materials has been hindered by issues such as poor colloidal stability of graphene in liquid media, weak interactions between graphene and the host polymers as well as the lack of scalable and economical graphene synthesis routes. Chlorosulfonic acid (CSA) can spontaneously disperse graphene without the need for mechanical agitation, chemical functionalisation or surfactant stabilisation, 1 however is incompatible with most polymers and organic materials. Here, we demonstrate how poly( p -phenylene terephthalamide) (PPTA) - the polymer which constitutes Kevlar - can be co-processed with graphene in CSA and wet-spun into nanocomposite fibres with minimal aggregation of graphene. Chlorosulfonic acid, an effective graphene dispersant, can be employed to produce graphene-aramid composite fibres.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c9cc04548a</identifier><ispartof>Chemical communications (Cambridge, England), 2019-09, Vol.55 (78), p.1173-1176</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Roberts, Aled D</creatorcontrib><creatorcontrib>Kelly, Paul</creatorcontrib><creatorcontrib>Bain, Jennifer</creatorcontrib><creatorcontrib>Morrison, John J</creatorcontrib><creatorcontrib>Wimpenny, Ian</creatorcontrib><creatorcontrib>Barrow, Mike</creatorcontrib><creatorcontrib>Woodward, Robert T</creatorcontrib><creatorcontrib>Gresil, Matthieu</creatorcontrib><creatorcontrib>Blanford, Christopher</creatorcontrib><creatorcontrib>Hay, Sam</creatorcontrib><creatorcontrib>Blaker, Jonny J</creatorcontrib><creatorcontrib>Yeates, Steve G</creatorcontrib><creatorcontrib>Scrutton, Nigel S</creatorcontrib><title>Graphene-aramid nanocomposite fibres superacid co-processing</title><title>Chemical communications (Cambridge, England)</title><description>The development of graphene-polymer nanocomposite materials has been hindered by issues such as poor colloidal stability of graphene in liquid media, weak interactions between graphene and the host polymers as well as the lack of scalable and economical graphene synthesis routes. Chlorosulfonic acid (CSA) can spontaneously disperse graphene without the need for mechanical agitation, chemical functionalisation or surfactant stabilisation, 1 however is incompatible with most polymers and organic materials. Here, we demonstrate how poly( p -phenylene terephthalamide) (PPTA) - the polymer which constitutes Kevlar - can be co-processed with graphene in CSA and wet-spun into nanocomposite fibres with minimal aggregation of graphene. Chlorosulfonic acid, an effective graphene dispersant, can be employed to produce graphene-aramid composite fibres.</description><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFjr0KwjAURoMoWH8Wd6EvEE1Ioi24iT8P4OBWrjHViE3CvTr49lYQHP2Wc-AsH2MTKWZSqHJuS2uFNrqADsukWmje-rH7cVPypdKmzwZEN9FOmiJjqx1CurrgOCA0_pwHCNHGJkXyD5fX_oSOcnomh2DbbCNPGK0j8uEyYr0a7uTGXw7ZdLs5rPccyVYJfQP4qn6X1L_-BiRbOkU</recordid><startdate>20190926</startdate><enddate>20190926</enddate><creator>Roberts, Aled D</creator><creator>Kelly, Paul</creator><creator>Bain, Jennifer</creator><creator>Morrison, John J</creator><creator>Wimpenny, Ian</creator><creator>Barrow, Mike</creator><creator>Woodward, Robert T</creator><creator>Gresil, Matthieu</creator><creator>Blanford, Christopher</creator><creator>Hay, Sam</creator><creator>Blaker, Jonny J</creator><creator>Yeates, Steve G</creator><creator>Scrutton, Nigel S</creator><scope/></search><sort><creationdate>20190926</creationdate><title>Graphene-aramid nanocomposite fibres superacid co-processing</title><author>Roberts, Aled D ; Kelly, Paul ; Bain, Jennifer ; Morrison, John J ; Wimpenny, Ian ; Barrow, Mike ; Woodward, Robert T ; Gresil, Matthieu ; Blanford, Christopher ; Hay, Sam ; Blaker, Jonny J ; Yeates, Steve G ; Scrutton, Nigel S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c9cc04548a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2019</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Roberts, Aled D</creatorcontrib><creatorcontrib>Kelly, Paul</creatorcontrib><creatorcontrib>Bain, Jennifer</creatorcontrib><creatorcontrib>Morrison, John J</creatorcontrib><creatorcontrib>Wimpenny, Ian</creatorcontrib><creatorcontrib>Barrow, Mike</creatorcontrib><creatorcontrib>Woodward, Robert T</creatorcontrib><creatorcontrib>Gresil, Matthieu</creatorcontrib><creatorcontrib>Blanford, Christopher</creatorcontrib><creatorcontrib>Hay, Sam</creatorcontrib><creatorcontrib>Blaker, Jonny J</creatorcontrib><creatorcontrib>Yeates, Steve G</creatorcontrib><creatorcontrib>Scrutton, Nigel S</creatorcontrib><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Roberts, Aled D</au><au>Kelly, Paul</au><au>Bain, Jennifer</au><au>Morrison, John J</au><au>Wimpenny, Ian</au><au>Barrow, Mike</au><au>Woodward, Robert T</au><au>Gresil, Matthieu</au><au>Blanford, Christopher</au><au>Hay, Sam</au><au>Blaker, Jonny J</au><au>Yeates, Steve G</au><au>Scrutton, Nigel S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Graphene-aramid nanocomposite fibres superacid co-processing</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2019-09-26</date><risdate>2019</risdate><volume>55</volume><issue>78</issue><spage>1173</spage><epage>1176</epage><pages>1173-1176</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>The development of graphene-polymer nanocomposite materials has been hindered by issues such as poor colloidal stability of graphene in liquid media, weak interactions between graphene and the host polymers as well as the lack of scalable and economical graphene synthesis routes. Chlorosulfonic acid (CSA) can spontaneously disperse graphene without the need for mechanical agitation, chemical functionalisation or surfactant stabilisation, 1 however is incompatible with most polymers and organic materials. Here, we demonstrate how poly( p -phenylene terephthalamide) (PPTA) - the polymer which constitutes Kevlar - can be co-processed with graphene in CSA and wet-spun into nanocomposite fibres with minimal aggregation of graphene. Chlorosulfonic acid, an effective graphene dispersant, can be employed to produce graphene-aramid composite fibres.</abstract><doi>10.1039/c9cc04548a</doi><tpages>4</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1359-7345
ispartof Chemical communications (Cambridge, England), 2019-09, Vol.55 (78), p.1173-1176
issn 1359-7345
1364-548X
language
recordid cdi_rsc_primary_c9cc04548a
source Royal Society of Chemistry
title Graphene-aramid nanocomposite fibres superacid co-processing
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-28T15%3A29%3A18IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-rsc&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Graphene-aramid%20nanocomposite%20fibres%20superacid%20co-processing&rft.jtitle=Chemical%20communications%20(Cambridge,%20England)&rft.au=Roberts,%20Aled%20D&rft.date=2019-09-26&rft.volume=55&rft.issue=78&rft.spage=1173&rft.epage=1176&rft.pages=1173-1176&rft.issn=1359-7345&rft.eissn=1364-548X&rft_id=info:doi/10.1039/c9cc04548a&rft_dat=%3Crsc%3Ec9cc04548a%3C/rsc%3E%3Cgrp_id%3Ecdi_FETCH-rsc_primary_c9cc04548a3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true