Enantioselective arylaryl coupling facilitated by chiral binuclear gold complexes

Herein, we report stoichiometric investigations embodying the first highly enantioselective arylaryl coupling facilitated by a gold complex. With up to 91% ee, this is the first demonstration of a transmetalation and C(sp 2 )C(sp 2 ) reductive elimination sequence with high enantioselectivity using...

Full description

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2019-10, Vol.55 (86), p.12988-12991
Main Authors: Himmelstrup, Jonas, Buendia, Mikkel B, Sun, Xing-Wen, Kramer, Sren
Format: Article
Language:
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page 12991
container_issue 86
container_start_page 12988
container_title Chemical communications (Cambridge, England)
container_volume 55
creator Himmelstrup, Jonas
Buendia, Mikkel B
Sun, Xing-Wen
Kramer, Sren
description Herein, we report stoichiometric investigations embodying the first highly enantioselective arylaryl coupling facilitated by a gold complex. With up to 91% ee, this is the first demonstration of a transmetalation and C(sp 2 )C(sp 2 ) reductive elimination sequence with high enantioselectivity using a gold complex. The results offer a basis for development of enantioselective gold-catalyzed arylaryl coupling reactions. The first example of highly enantioselective arylaryl coupling mediated by chiral gold complexes is reported.
doi_str_mv 10.1039/c9cc07175j
format article
fullrecord <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_c9cc07175j</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>c9cc07175j</sourcerecordid><originalsourceid>FETCH-rsc_primary_c9cc07175j3</originalsourceid><addsrcrecordid>eNqFTs0KgkAYXKIg-7l0D_YFLBfd1HMYXYMO3WT9XG3l84fdNfLtUwg6NjDMwAzDELJj3oF5fnyEGMALWcirGXGYfwpcHkSP-eR57IZ-wJdkZUzljWA8csgtaURjVWskSrDqJanQA06k0PYdqqakhQCFygorc5oNFJ5KC6SZanpAKTQtW8zHdt2hfEuzIYtCoJHbr67J_pLcz1dXG0g7repxPP399P_lH_3AQo0</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Enantioselective arylaryl coupling facilitated by chiral binuclear gold complexes</title><source>Royal Society of Chemistry</source><creator>Himmelstrup, Jonas ; Buendia, Mikkel B ; Sun, Xing-Wen ; Kramer, Sren</creator><creatorcontrib>Himmelstrup, Jonas ; Buendia, Mikkel B ; Sun, Xing-Wen ; Kramer, Sren</creatorcontrib><description>Herein, we report stoichiometric investigations embodying the first highly enantioselective arylaryl coupling facilitated by a gold complex. With up to 91% ee, this is the first demonstration of a transmetalation and C(sp 2 )C(sp 2 ) reductive elimination sequence with high enantioselectivity using a gold complex. The results offer a basis for development of enantioselective gold-catalyzed arylaryl coupling reactions. The first example of highly enantioselective arylaryl coupling mediated by chiral gold complexes is reported.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c9cc07175j</identifier><ispartof>Chemical communications (Cambridge, England), 2019-10, Vol.55 (86), p.12988-12991</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Himmelstrup, Jonas</creatorcontrib><creatorcontrib>Buendia, Mikkel B</creatorcontrib><creatorcontrib>Sun, Xing-Wen</creatorcontrib><creatorcontrib>Kramer, Sren</creatorcontrib><title>Enantioselective arylaryl coupling facilitated by chiral binuclear gold complexes</title><title>Chemical communications (Cambridge, England)</title><description>Herein, we report stoichiometric investigations embodying the first highly enantioselective arylaryl coupling facilitated by a gold complex. With up to 91% ee, this is the first demonstration of a transmetalation and C(sp 2 )C(sp 2 ) reductive elimination sequence with high enantioselectivity using a gold complex. The results offer a basis for development of enantioselective gold-catalyzed arylaryl coupling reactions. The first example of highly enantioselective arylaryl coupling mediated by chiral gold complexes is reported.</description><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFTs0KgkAYXKIg-7l0D_YFLBfd1HMYXYMO3WT9XG3l84fdNfLtUwg6NjDMwAzDELJj3oF5fnyEGMALWcirGXGYfwpcHkSP-eR57IZ-wJdkZUzljWA8csgtaURjVWskSrDqJanQA06k0PYdqqakhQCFygorc5oNFJ5KC6SZanpAKTQtW8zHdt2hfEuzIYtCoJHbr67J_pLcz1dXG0g7repxPP399P_lH_3AQo0</recordid><startdate>20191024</startdate><enddate>20191024</enddate><creator>Himmelstrup, Jonas</creator><creator>Buendia, Mikkel B</creator><creator>Sun, Xing-Wen</creator><creator>Kramer, Sren</creator><scope/></search><sort><creationdate>20191024</creationdate><title>Enantioselective arylaryl coupling facilitated by chiral binuclear gold complexes</title><author>Himmelstrup, Jonas ; Buendia, Mikkel B ; Sun, Xing-Wen ; Kramer, Sren</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c9cc07175j3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2019</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Himmelstrup, Jonas</creatorcontrib><creatorcontrib>Buendia, Mikkel B</creatorcontrib><creatorcontrib>Sun, Xing-Wen</creatorcontrib><creatorcontrib>Kramer, Sren</creatorcontrib><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Himmelstrup, Jonas</au><au>Buendia, Mikkel B</au><au>Sun, Xing-Wen</au><au>Kramer, Sren</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enantioselective arylaryl coupling facilitated by chiral binuclear gold complexes</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2019-10-24</date><risdate>2019</risdate><volume>55</volume><issue>86</issue><spage>12988</spage><epage>12991</epage><pages>12988-12991</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Herein, we report stoichiometric investigations embodying the first highly enantioselective arylaryl coupling facilitated by a gold complex. With up to 91% ee, this is the first demonstration of a transmetalation and C(sp 2 )C(sp 2 ) reductive elimination sequence with high enantioselectivity using a gold complex. The results offer a basis for development of enantioselective gold-catalyzed arylaryl coupling reactions. The first example of highly enantioselective arylaryl coupling mediated by chiral gold complexes is reported.</abstract><doi>10.1039/c9cc07175j</doi><tpages>4</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1359-7345
ispartof Chemical communications (Cambridge, England), 2019-10, Vol.55 (86), p.12988-12991
issn 1359-7345
1364-548X
language
recordid cdi_rsc_primary_c9cc07175j
source Royal Society of Chemistry
title Enantioselective arylaryl coupling facilitated by chiral binuclear gold complexes
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-20T03%3A05%3A42IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-rsc&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Enantioselective%20arylaryl%20coupling%20facilitated%20by%20chiral%20binuclear%20gold%20complexes&rft.jtitle=Chemical%20communications%20(Cambridge,%20England)&rft.au=Himmelstrup,%20Jonas&rft.date=2019-10-24&rft.volume=55&rft.issue=86&rft.spage=12988&rft.epage=12991&rft.pages=12988-12991&rft.issn=1359-7345&rft.eissn=1364-548X&rft_id=info:doi/10.1039/c9cc07175j&rft_dat=%3Crsc%3Ec9cc07175j%3C/rsc%3E%3Cgrp_id%3Ecdi_FETCH-rsc_primary_c9cc07175j3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true