The chemistry of guanidinate complexes of the platinum group metals

In this Perspective article, recent advances in the chemistry of platinum group metal complexes containing mono- and dianionic guanidinate ligands, i.e. [(RN) 2 C-NR 2 ] − and [(RN) 2 C&z.dbd;NR] 2− , respectively, are presented. Synthetic and structural aspects, reactivity studies, and applicat...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2019-06, Vol.48 (25), p.921-936
Main Authors: Francos, Javier, Cadierno, Victorio
Format: Article
Language:English
Subjects:
Coordination compounds
Organic chemistry
Platinum
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Summary:In this Perspective article, recent advances in the chemistry of platinum group metal complexes containing mono- and dianionic guanidinate ligands, i.e. [(RN) 2 C-NR 2 ] − and [(RN) 2 C&z.dbd;NR] 2− , respectively, are presented. Synthetic and structural aspects, reactivity studies, and applications of these compounds are discussed. In the present Perspective article, synthetic and structural aspects, reactivity studies and applications of platinum group metal complexes containing guanidinate ligands are discussed.
ISSN:1477-9226
1477-9234
DOI:10.1039/c9dt01289c