A mixed-spin spin-crossover thiozolylimine [FeL] cage

The self-assembly of a mixed-spin [Fe 4 L 6 ] 8+ tetrahedral cage is reported. The cage undergoes temperature induced spin-crossover with a 29 K hystereisis. Variable temperature X-ray photoelectron spectroscopy (VT-XPS), combined with SQUID data, allowed differentiation between the surface and bulk...

Full description

Saved in:
Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2019-07, Vol.48 (27), p.9935-9938
Main Authors: Li, Li, Craze, Alexander R, Mustonen, Outi, Zenno, Hikaru, Whittaker, Jacob J, Hayami, Shinya, Lindoy, Leonard F, Marjo, Christopher E, Clegg, Jack K, Aldrich-Wright, Janice R, Li, Feng
Format: Article
Language:English
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The self-assembly of a mixed-spin [Fe 4 L 6 ] 8+ tetrahedral cage is reported. The cage undergoes temperature induced spin-crossover with a 29 K hystereisis. Variable temperature X-ray photoelectron spectroscopy (VT-XPS), combined with SQUID data, allowed differentiation between the surface and bulk magnetic properties. A mixed-spin spin-crossover thiozolylimine [Fe 4 L 6 ] 8+ tetrahedral cage is reported.
ISSN:1477-9226
1477-9234
DOI:10.1039/c9dt01947b