Pyrenediones as versatile photocatalysts for oxygenation reactions with generation of hydrogen peroxide under visible light

Pyrenediones (PYDs) are efficient photocatalysts for three oxygenation reactions: epoxidation of electron deficient olefins, oxidative hydroxylation of organoborons, and oxidation of sulfides via in situ generation of H 2 O 2 under visible light irradiation, using oxygen as a terminal oxidant and IP...

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Published in:Green chemistry : an international journal and green chemistry resource : GC 2020-01, Vol.22 (1), p.22-27
Main Authors: Zhang, Yuannian, Yang, Xin, Tang, Haidi, Liang, Dong, Wu, Jie, Huang, Dejian
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Summary:Pyrenediones (PYDs) are efficient photocatalysts for three oxygenation reactions: epoxidation of electron deficient olefins, oxidative hydroxylation of organoborons, and oxidation of sulfides via in situ generation of H 2 O 2 under visible light irradiation, using oxygen as a terminal oxidant and IPA as a solvent and a hydrogen donor. Pyrenediones (PYDs) are efficient photocatalysts for three oxygenation reactions: epoxidation of electron deficient olefins, oxidative hydroxylation of organoborons and oxidation of sulfides via in situ generation of H 2 O 2 from O 2 under visible light irradiation.
ISSN:1463-9262
1463-9270
DOI:10.1039/c9gc03152a