Loading…
A series of metal-organic loops templated by [SiMoO] and [β-MoO] anions using double chelating ligands: amperometric sensing and selective photocatalytic properties
By using the double chelating ligands 2,3-di-pyridin-2-yl-pyrazine (L 1 ) and 2,3-di-pyridin-2-yl-quinoxaline (L 2 ), six new polyoxometalate-based compounds, namely [Ag I 4 (L 1 ) 4 (SiMo 12 O 40 )] ( 1 ), [Cu II 6 (L 1 ) 6 (H 2 O) 6 (SiMo 12 O 40 ) 3 ]·6H 2 O ( 2 ), [Cu II (L 1 )(H 2 O)(β-Mo 8 O 2...
Saved in:
| Published in: | New journal of chemistry 2019-07, Vol.43 (25), p.998-9988 |
|---|---|
| Main Authors: | , , , , , , |
| Format: | Article |
| Language: | English |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | |
|---|---|
| cites | |
| container_end_page | 9988 |
| container_issue | 25 |
| container_start_page | 998 |
| container_title | New journal of chemistry |
| container_volume | 43 |
| creator | Tian, Ai-xiang Fu, Yu-bo Cui, Hong-tao Ying, Jun Yang, Meng-le Yang, Yan Wang, Xiu-li |
| description | By using the double chelating ligands 2,3-di-pyridin-2-yl-pyrazine (L
1
) and 2,3-di-pyridin-2-yl-quinoxaline (L
2
), six new polyoxometalate-based compounds, namely [Ag
I
4
(L
1
)
4
(SiMo
12
O
40
)] (
1
), [Cu
II
6
(L
1
)
6
(H
2
O)
6
(SiMo
12
O
40
)
3
]·6H
2
O (
2
), [Cu
II
(L
1
)(H
2
O)(β-Mo
8
O
26
)
0.5
] (
3
), [Ag
I
2
(L
2
)(β-Mo
8
O
26
)
0.5
] (
4
), [Cu
II
(L
2
)(β-Mo
8
O
26
)
0.5
] (
5
) and [Zn
II
(L
2
)(β-Mo
8
O
26
)
0.5
] (
6
), have been hydrothermally synthesized and characterized by single-crystal X-ray diffraction analysis, IR spectra and elemental analyses. Using the double chelating ligand L
1
, compounds
1-3
were obtained. In compound
1
, there is a tetra-nuclear Ag loop with four Ag atoms linked by four L
1
ligands. The [SiMo
12
O
40
]
4−
anions are sandwiched by these loops alternately. Compound
2
has a hexa-nuclear shield-like Cu cluster, in which six Cu atoms are connected by six L
1
ligands. The channel formed by the packing hexa-nuclear loops accommodates the [SiMo
12
O
40
]
4−
anions. By using [β-Mo
8
O
26
]
4−
instead of [SiMo
12
O
40
]
4−
, compound
3
was obtained containing a zigzag metal-organic chain. The chains are linked by [β-Mo
8
O
26
]
4−
anions to construct a layer. By changing L
1
to L
2
, compounds
4-6
containing metal-organic loops were built. In compound
4
, two L
2
ligands are linked by two Ag atoms to form a bi-nuclear loop. The [β-Mo
8
O
26
]
4−
anions as tetra-dentate inorganic subunits link bi-nuclear loops to build a 2D layer. Compounds
5
and
6
are isostructural, with bi-nuclear Cu/Zn-L
2
loops connected by [β-Mo
8
O
26
]
4−
anions alternately to construct a 1D chain. In addition, we also studied the electrochemical properties and selective photocatalytic properties of compounds
1-6
.
By changing the POM anions and TM ions, a series of compounds with multi-nuclear loops was formed. |
| doi_str_mv | 10.1039/c9nj02224d |
| format | article |
| fullrecord | <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_c9nj02224d</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>c9nj02224d</sourcerecordid><originalsourceid>FETCH-LOGICAL-r203t-8bf3d879432802b9137f962192a21d1554fc659d5bd74570cbc7c80f5de07be43</originalsourceid><addsrcrecordid>eNp9kMtKAzEUhoMoWKsb90J8gNHc5hJ3pXiDShfqqkjJJGfalOlkSFKhD-QL-CA-k6kW3Lk6F_7_Oz8HoXNKrijh8lrLbkUYY8IcoAHlhcwkK-hh6qkQGclFcYxOQlgRQmlZ0AH6GOEA3kLArsFriKrNnF-ozmrcOtcHHGHdtyqCwfUWz57tk5u-YdUZPPv6zPaDdV3Am2C7BTZuU7eA9RKSabdobaKZcIPVugfv0gmf2AG6H_kOFKAFHe074H7potMqhdjGJOq9S5aYwp2io0a1Ac72dYhe725fxg_ZZHr_OB5NMs8Ij1lVN9xUpRScVYTVkvKykQWjkilGDc1z0egilyavTSnykuhal7oiTW6AlDUIPkSXv1wf9Lz3dq38dv7303lvmqS5-E_DvwG3dnpO</addsrcrecordid><sourcetype>Enrichment Source</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>A series of metal-organic loops templated by [SiMoO] and [β-MoO] anions using double chelating ligands: amperometric sensing and selective photocatalytic properties</title><source>Royal Society of Chemistry</source><creator>Tian, Ai-xiang ; Fu, Yu-bo ; Cui, Hong-tao ; Ying, Jun ; Yang, Meng-le ; Yang, Yan ; Wang, Xiu-li</creator><creatorcontrib>Tian, Ai-xiang ; Fu, Yu-bo ; Cui, Hong-tao ; Ying, Jun ; Yang, Meng-le ; Yang, Yan ; Wang, Xiu-li</creatorcontrib><description>By using the double chelating ligands 2,3-di-pyridin-2-yl-pyrazine (L
1
) and 2,3-di-pyridin-2-yl-quinoxaline (L
2
), six new polyoxometalate-based compounds, namely [Ag
I
4
(L
1
)
4
(SiMo
12
O
40
)] (
1
), [Cu
II
6
(L
1
)
6
(H
2
O)
6
(SiMo
12
O
40
)
3
]·6H
2
O (
2
), [Cu
II
(L
1
)(H
2
O)(β-Mo
8
O
26
)
0.5
] (
3
), [Ag
I
2
(L
2
)(β-Mo
8
O
26
)
0.5
] (
4
), [Cu
II
(L
2
)(β-Mo
8
O
26
)
0.5
] (
5
) and [Zn
II
(L
2
)(β-Mo
8
O
26
)
0.5
] (
6
), have been hydrothermally synthesized and characterized by single-crystal X-ray diffraction analysis, IR spectra and elemental analyses. Using the double chelating ligand L
1
, compounds
1-3
were obtained. In compound
1
, there is a tetra-nuclear Ag loop with four Ag atoms linked by four L
1
ligands. The [SiMo
12
O
40
]
4−
anions are sandwiched by these loops alternately. Compound
2
has a hexa-nuclear shield-like Cu cluster, in which six Cu atoms are connected by six L
1
ligands. The channel formed by the packing hexa-nuclear loops accommodates the [SiMo
12
O
40
]
4−
anions. By using [β-Mo
8
O
26
]
4−
instead of [SiMo
12
O
40
]
4−
, compound
3
was obtained containing a zigzag metal-organic chain. The chains are linked by [β-Mo
8
O
26
]
4−
anions to construct a layer. By changing L
1
to L
2
, compounds
4-6
containing metal-organic loops were built. In compound
4
, two L
2
ligands are linked by two Ag atoms to form a bi-nuclear loop. The [β-Mo
8
O
26
]
4−
anions as tetra-dentate inorganic subunits link bi-nuclear loops to build a 2D layer. Compounds
5
and
6
are isostructural, with bi-nuclear Cu/Zn-L
2
loops connected by [β-Mo
8
O
26
]
4−
anions alternately to construct a 1D chain. In addition, we also studied the electrochemical properties and selective photocatalytic properties of compounds
1-6
.
By changing the POM anions and TM ions, a series of compounds with multi-nuclear loops was formed.</description><identifier>ISSN: 1144-0546</identifier><identifier>EISSN: 1369-9261</identifier><identifier>DOI: 10.1039/c9nj02224d</identifier><language>eng</language><ispartof>New journal of chemistry, 2019-07, Vol.43 (25), p.998-9988</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27922,27923</link.rule.ids></links><search><creatorcontrib>Tian, Ai-xiang</creatorcontrib><creatorcontrib>Fu, Yu-bo</creatorcontrib><creatorcontrib>Cui, Hong-tao</creatorcontrib><creatorcontrib>Ying, Jun</creatorcontrib><creatorcontrib>Yang, Meng-le</creatorcontrib><creatorcontrib>Yang, Yan</creatorcontrib><creatorcontrib>Wang, Xiu-li</creatorcontrib><title>A series of metal-organic loops templated by [SiMoO] and [β-MoO] anions using double chelating ligands: amperometric sensing and selective photocatalytic properties</title><title>New journal of chemistry</title><description>By using the double chelating ligands 2,3-di-pyridin-2-yl-pyrazine (L
1
) and 2,3-di-pyridin-2-yl-quinoxaline (L
2
), six new polyoxometalate-based compounds, namely [Ag
I
4
(L
1
)
4
(SiMo
12
O
40
)] (
1
), [Cu
II
6
(L
1
)
6
(H
2
O)
6
(SiMo
12
O
40
)
3
]·6H
2
O (
2
), [Cu
II
(L
1
)(H
2
O)(β-Mo
8
O
26
)
0.5
] (
3
), [Ag
I
2
(L
2
)(β-Mo
8
O
26
)
0.5
] (
4
), [Cu
II
(L
2
)(β-Mo
8
O
26
)
0.5
] (
5
) and [Zn
II
(L
2
)(β-Mo
8
O
26
)
0.5
] (
6
), have been hydrothermally synthesized and characterized by single-crystal X-ray diffraction analysis, IR spectra and elemental analyses. Using the double chelating ligand L
1
, compounds
1-3
were obtained. In compound
1
, there is a tetra-nuclear Ag loop with four Ag atoms linked by four L
1
ligands. The [SiMo
12
O
40
]
4−
anions are sandwiched by these loops alternately. Compound
2
has a hexa-nuclear shield-like Cu cluster, in which six Cu atoms are connected by six L
1
ligands. The channel formed by the packing hexa-nuclear loops accommodates the [SiMo
12
O
40
]
4−
anions. By using [β-Mo
8
O
26
]
4−
instead of [SiMo
12
O
40
]
4−
, compound
3
was obtained containing a zigzag metal-organic chain. The chains are linked by [β-Mo
8
O
26
]
4−
anions to construct a layer. By changing L
1
to L
2
, compounds
4-6
containing metal-organic loops were built. In compound
4
, two L
2
ligands are linked by two Ag atoms to form a bi-nuclear loop. The [β-Mo
8
O
26
]
4−
anions as tetra-dentate inorganic subunits link bi-nuclear loops to build a 2D layer. Compounds
5
and
6
are isostructural, with bi-nuclear Cu/Zn-L
2
loops connected by [β-Mo
8
O
26
]
4−
anions alternately to construct a 1D chain. In addition, we also studied the electrochemical properties and selective photocatalytic properties of compounds
1-6
.
By changing the POM anions and TM ions, a series of compounds with multi-nuclear loops was formed.</description><issn>1144-0546</issn><issn>1369-9261</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNp9kMtKAzEUhoMoWKsb90J8gNHc5hJ3pXiDShfqqkjJJGfalOlkSFKhD-QL-CA-k6kW3Lk6F_7_Oz8HoXNKrijh8lrLbkUYY8IcoAHlhcwkK-hh6qkQGclFcYxOQlgRQmlZ0AH6GOEA3kLArsFriKrNnF-ozmrcOtcHHGHdtyqCwfUWz57tk5u-YdUZPPv6zPaDdV3Am2C7BTZuU7eA9RKSabdobaKZcIPVugfv0gmf2AG6H_kOFKAFHe074H7potMqhdjGJOq9S5aYwp2io0a1Ac72dYhe725fxg_ZZHr_OB5NMs8Ij1lVN9xUpRScVYTVkvKykQWjkilGDc1z0egilyavTSnykuhal7oiTW6AlDUIPkSXv1wf9Lz3dq38dv7303lvmqS5-E_DvwG3dnpO</recordid><startdate>20190707</startdate><enddate>20190707</enddate><creator>Tian, Ai-xiang</creator><creator>Fu, Yu-bo</creator><creator>Cui, Hong-tao</creator><creator>Ying, Jun</creator><creator>Yang, Meng-le</creator><creator>Yang, Yan</creator><creator>Wang, Xiu-li</creator><scope/></search><sort><creationdate>20190707</creationdate><title>A series of metal-organic loops templated by [SiMoO] and [β-MoO] anions using double chelating ligands: amperometric sensing and selective photocatalytic properties</title><author>Tian, Ai-xiang ; Fu, Yu-bo ; Cui, Hong-tao ; Ying, Jun ; Yang, Meng-le ; Yang, Yan ; Wang, Xiu-li</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-r203t-8bf3d879432802b9137f962192a21d1554fc659d5bd74570cbc7c80f5de07be43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tian, Ai-xiang</creatorcontrib><creatorcontrib>Fu, Yu-bo</creatorcontrib><creatorcontrib>Cui, Hong-tao</creatorcontrib><creatorcontrib>Ying, Jun</creatorcontrib><creatorcontrib>Yang, Meng-le</creatorcontrib><creatorcontrib>Yang, Yan</creatorcontrib><creatorcontrib>Wang, Xiu-li</creatorcontrib><jtitle>New journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tian, Ai-xiang</au><au>Fu, Yu-bo</au><au>Cui, Hong-tao</au><au>Ying, Jun</au><au>Yang, Meng-le</au><au>Yang, Yan</au><au>Wang, Xiu-li</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A series of metal-organic loops templated by [SiMoO] and [β-MoO] anions using double chelating ligands: amperometric sensing and selective photocatalytic properties</atitle><jtitle>New journal of chemistry</jtitle><date>2019-07-07</date><risdate>2019</risdate><volume>43</volume><issue>25</issue><spage>998</spage><epage>9988</epage><pages>998-9988</pages><issn>1144-0546</issn><eissn>1369-9261</eissn><abstract>By using the double chelating ligands 2,3-di-pyridin-2-yl-pyrazine (L
1
) and 2,3-di-pyridin-2-yl-quinoxaline (L
2
), six new polyoxometalate-based compounds, namely [Ag
I
4
(L
1
)
4
(SiMo
12
O
40
)] (
1
), [Cu
II
6
(L
1
)
6
(H
2
O)
6
(SiMo
12
O
40
)
3
]·6H
2
O (
2
), [Cu
II
(L
1
)(H
2
O)(β-Mo
8
O
26
)
0.5
] (
3
), [Ag
I
2
(L
2
)(β-Mo
8
O
26
)
0.5
] (
4
), [Cu
II
(L
2
)(β-Mo
8
O
26
)
0.5
] (
5
) and [Zn
II
(L
2
)(β-Mo
8
O
26
)
0.5
] (
6
), have been hydrothermally synthesized and characterized by single-crystal X-ray diffraction analysis, IR spectra and elemental analyses. Using the double chelating ligand L
1
, compounds
1-3
were obtained. In compound
1
, there is a tetra-nuclear Ag loop with four Ag atoms linked by four L
1
ligands. The [SiMo
12
O
40
]
4−
anions are sandwiched by these loops alternately. Compound
2
has a hexa-nuclear shield-like Cu cluster, in which six Cu atoms are connected by six L
1
ligands. The channel formed by the packing hexa-nuclear loops accommodates the [SiMo
12
O
40
]
4−
anions. By using [β-Mo
8
O
26
]
4−
instead of [SiMo
12
O
40
]
4−
, compound
3
was obtained containing a zigzag metal-organic chain. The chains are linked by [β-Mo
8
O
26
]
4−
anions to construct a layer. By changing L
1
to L
2
, compounds
4-6
containing metal-organic loops were built. In compound
4
, two L
2
ligands are linked by two Ag atoms to form a bi-nuclear loop. The [β-Mo
8
O
26
]
4−
anions as tetra-dentate inorganic subunits link bi-nuclear loops to build a 2D layer. Compounds
5
and
6
are isostructural, with bi-nuclear Cu/Zn-L
2
loops connected by [β-Mo
8
O
26
]
4−
anions alternately to construct a 1D chain. In addition, we also studied the electrochemical properties and selective photocatalytic properties of compounds
1-6
.
By changing the POM anions and TM ions, a series of compounds with multi-nuclear loops was formed.</abstract><doi>10.1039/c9nj02224d</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1144-0546 |
| ispartof | New journal of chemistry, 2019-07, Vol.43 (25), p.998-9988 |
| issn | 1144-0546 1369-9261 |
| language | eng |
| recordid | cdi_rsc_primary_c9nj02224d |
| source | Royal Society of Chemistry |
| title | A series of metal-organic loops templated by [SiMoO] and [β-MoO] anions using double chelating ligands: amperometric sensing and selective photocatalytic properties |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-14T04%3A01%3A07IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-rsc&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20series%20of%20metal-organic%20loops%20templated%20by%20%5BSiMoO%5D%20and%20%5B%CE%B2-MoO%5D%20anions%20using%20double%20chelating%20ligands:%20amperometric%20sensing%20and%20selective%20photocatalytic%20properties&rft.jtitle=New%20journal%20of%20chemistry&rft.au=Tian,%20Ai-xiang&rft.date=2019-07-07&rft.volume=43&rft.issue=25&rft.spage=998&rft.epage=9988&rft.pages=998-9988&rft.issn=1144-0546&rft.eissn=1369-9261&rft_id=info:doi/10.1039/c9nj02224d&rft_dat=%3Crsc%3Ec9nj02224d%3C/rsc%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-r203t-8bf3d879432802b9137f962192a21d1554fc659d5bd74570cbc7c80f5de07be43%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |