MnO nanoparticle mediated colorimetric turn-off determination of ascorbic acid

• Published in: New journal of chemistry 2019-12, Vol.44 (2), p.381-386
• Main Authors: Wang, Qi, Ma, Xulu, Lv, Houhua, Wei, Awen, Wu, Tingxuan, Ding, Lifeng, Ma, Xiang, Ma, Chunlei
• Format: Article
• Language: English
• ISSN: 1144-0546; 1369-9261
• DOI: 10.1039/c9nj05751j

Ascorbic acid (AA) is an esstential micronutrient in the human body and participates in vital processes. It can only be supplemented by external intake, making the determination of AA in food or beverages of significance. In the present work, MnO 2 nanoparticle (MnO 2 NP) based turn-off colorimetry was established for AA determination on the basis of AA-stimulated inhibition of catalytic oxidation. MnO 2 NPs were synthesized through a biotemplating method and displayed effective catalytic oxidation activity for oxidation of TMB, triggering a chromogenic reaction. Interestingly, the introduction of AA induced the decomposition of MnO 2 NPs and as a consequence decreased the colour. Therefore, sensitive and selective turn-off colorimetry for AA detection was established and a satisfactory linear range of 0.5-30 μM with a detection limit of 0.28 μM was obtained. This MnO 2 NP-based method was activated via a novel sensing principle, complementing and facilitating colorimetry for AA. The scheme of the turn-off colorimetric response of AA to the TMB-MnO 2 NP system.