Photocatalytic activity of exfoliated graphiteTiO nanoparticle composites

• Published in: Nanoscale 2019-10, Vol.11 (41), p.1931-19314
• Main Authors: Guidetti, Gloria, Pogna, Eva A. A, Lombardi, Lucia, Tomarchio, Flavia, Polishchuk, Iryna, Joosten, Rick R. M, Ianiro, Alessandro, Soavi, Giancarlo, Sommerdijk, Nico A. J. M, Friedrich, Heiner, Pokroy, Boaz, Ott, Anna K, Goisis, Marco, Zerbetto, Francesco, Falini, Giuseppe, Calvaresi, Matteo, Ferrari, Andrea C, Cerullo, Giulio, Montalti, Marco
• Format: Article
• ISSN: 2040-3364; 2040-3372
• DOI: 10.1039/c9nr06760d

We investigate the photocatalytic performance of composites prepared in a one-step process by liquid-phase exfoliation of graphite in the presence of TiO 2 nanoparticles (NPs) at atmospheric pressure and in water, without heating or adding any surfactant, and starting from low-cost commercial reagents. These show enhanced photocatalytic activity, degrading up to 40% more pollutants with respect to the starting TiO 2 -NPs, in the case of a model dye target, and up to 70% more pollutants in the case of nitrogen oxides. In order to understand the photo-physical mechanisms underlying this enhancement, we investigate the photo-generation of reactive species (trapped holes and electrons) by ultrafast transient absorption spectroscopy. We observe an electron transfer process from TiO 2 to the graphite flakes within the first picoseconds of the relaxation dynamics, which causes the decrease of the charge recombination rate, and increases the efficiency of the reactive species photo-production. We report the photocatalytic performance of composites prepared in a one-step process by liquid phase exfoliation of graphite and TiO 2 at atmospheric pressure and in water, without heat or surfactants, starting from low-cost commercial reagents.