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Rhodium()-catalyzed vinylation/[2 + 1] carbocyclization of 1,6-enynes with α-diazocarbonyl compounds
A sequential Rh( i )-catalyzed vinylation/[2 + 1]carbocyclization between enynes and diazo compounds has been developed. This transformation features a wide range of enynes and acceptor/acceptor diazo compounds, providing easy access to versatile vinyl-substituted azabicyclo[3.1.0]hexanes having a b...
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Published in: | Organic & biomolecular chemistry 2019-07, Vol.17 (29), p.742-754 |
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Main Authors: | , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | A sequential Rh(
i
)-catalyzed vinylation/[2 + 1]carbocyclization between enynes and diazo compounds has been developed. This transformation features a wide range of enynes and acceptor/acceptor diazo compounds, providing easy access to versatile vinyl-substituted azabicyclo[3.1.0]hexanes having a broad tolerance to functional groups.
Rh(
i
)-catalyzed coupling-cyclization of enynes with diazo compounds has been developed to obtain versatile vinyl-substituted azabicyclo[3.1.0]hexanes. |
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ISSN: | 1477-0520 1477-0539 |
DOI: | 10.1039/c9ob01028a |