Visible-light-mediated difunctionalization of vinylcyclopropanes for the synthesis of 1-sulfonylmethyl-3,4-dihydronaphthalenes

An efficient method for visible-light-mediated sulfonylation/arylation of the CC -bond in vinylcyclopropanes with sulfonyl chlorides to synthesize 1-sulfonylmethyl-substituted 3,4-dihydronaphalenes has been developed. A radical-type pathway has been proved in this transformation. This difunctionaliz...

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Bibliographic Details
Published in:Organic & biomolecular chemistry 2019-08, Vol.17 (34), p.7918-7926
Main Authors: Wang, Qiao-Lin, Zhang, Wen-Zheng, Zhou, Quan, Zhou, Cong-Shan, Xiong, Bi-Quan, Tang, Ke-Wen, Liu, Yu
Format: Article
Language:English
Subjects:
Chlorides
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Summary:An efficient method for visible-light-mediated sulfonylation/arylation of the CC -bond in vinylcyclopropanes with sulfonyl chlorides to synthesize 1-sulfonylmethyl-substituted 3,4-dihydronaphalenes has been developed. A radical-type pathway has been proved in this transformation. This difunctionalization procedure shows a series of advantages, such as the use of commercially and easily available sulfonyl chlorides, mild conditions, and eco-friendly energy. An efficient method for the visible-light-mediated sulfonylation/arylation of the CC -bond in vinylcyclopropanes with sulfonyl chlorides to synthesize 1-sulfonylmethyl-substituted 3,4-dihydronaphalenes has been developed.
ISSN:1477-0520
1477-0539
DOI:10.1039/c9ob01321k