Loading…
A new member of a class of rod-like Mn single molecule magnets using 2-(pyridine-2-ly)propan-2-ol
This paper reports on the synthesis, structure and magnetic properties of a new type of rod like Mn 12 metal cluster, [Mn 12 O 7 (OH) 2 (OMe) 2 (dmhmp) 4 (O 2 CPh) 11 (H 2 O)] ( 6 ) where the ligand (dmhmpH) is 2-(pyridine-2-yl)propan-2-ol. Compound ( 6 ) was obtained by reacting MnCl 2 ·4H 2 O with...
Saved in:
| Published in: | RSC advances 2019-11, Vol.9 (65), p.3774-37746 |
|---|---|
| Main Authors: | , , , , , , |
| Format: | Article |
| Language: | English |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | |
|---|---|
| cites | |
| container_end_page | 37746 |
| container_issue | 65 |
| container_start_page | 3774 |
| container_title | RSC advances |
| container_volume | 9 |
| creator | Yang, En-Che Huang, Shi-Yi Wernsdorfer, Wolfgang Hong, Ling-Xuan Damjanovic, Marko Niekamp, Lukas Lee, Gene-Hsiang |
| description | This paper reports on the synthesis, structure and magnetic properties of a new type of rod like Mn
12
metal cluster, [Mn
12
O
7
(OH)
2
(OMe)
2
(dmhmp)
4
(O
2
CPh)
11
(H
2
O)] (
6
) where the ligand (dmhmpH) is 2-(pyridine-2-yl)propan-2-ol. Compound (
6
) was obtained by reacting MnCl
2
·4H
2
O with dmhmpH in the presence of benzoic salt and Et
3
N. The resulting crystalline material is assigned to the triclinic space group
P
1&cmb.macr;. Although compound (
6
) displays ferromagnetic and antiferromagnetic competition behavior, this does not prevent the molecule from functioning as a single-molecule magnet (SMM). The SMM behavior is evidenced by observing frequency dependent out-of-phase ac signals as well as magnetization hysteresis loops at low temperatures in a micro-SQUID study. A brief comparison between all rod-like Mn
12
materials is also given in the manuscript.
A new member of rod-like Mn
12
molecules functions as a single molecule magnet. |
| doi_str_mv | 10.1039/c9ra06280g |
| format | article |
| fullrecord | <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_c9ra06280g</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>c9ra06280g</sourcerecordid><originalsourceid>FETCH-rsc_primary_c9ra06280g3</originalsourceid><addsrcrecordid>eNqFjrEKwjAURYMgKOriLjw3HaJpqsGOIoqLm3uJ7WuJpklILNK_twXBTe9yDpzlEjKN2CpicbLOEi-Z4DtW9siQs42gnIlkQCYh3Fk7sY24iIZE7sHgCyqsbujBFiAh0zKETr3NqVYPhIuBoEypESqrMas7kaXBZ4C6C8DpwjVe5cog5VQ3S-etk6Z1q8ekX0gdcPLhiMxOx-vhTH3IUudVJX2Tfu_G__v8V09dXsRvBShPWA</addsrcrecordid><sourcetype>Enrichment Source</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>A new member of a class of rod-like Mn single molecule magnets using 2-(pyridine-2-ly)propan-2-ol</title><source>PMC (PubMed Central)</source><creator>Yang, En-Che ; Huang, Shi-Yi ; Wernsdorfer, Wolfgang ; Hong, Ling-Xuan ; Damjanovic, Marko ; Niekamp, Lukas ; Lee, Gene-Hsiang</creator><creatorcontrib>Yang, En-Che ; Huang, Shi-Yi ; Wernsdorfer, Wolfgang ; Hong, Ling-Xuan ; Damjanovic, Marko ; Niekamp, Lukas ; Lee, Gene-Hsiang</creatorcontrib><description>This paper reports on the synthesis, structure and magnetic properties of a new type of rod like Mn
12
metal cluster, [Mn
12
O
7
(OH)
2
(OMe)
2
(dmhmp)
4
(O
2
CPh)
11
(H
2
O)] (
6
) where the ligand (dmhmpH) is 2-(pyridine-2-yl)propan-2-ol. Compound (
6
) was obtained by reacting MnCl
2
·4H
2
O with dmhmpH in the presence of benzoic salt and Et
3
N. The resulting crystalline material is assigned to the triclinic space group
P
1&cmb.macr;. Although compound (
6
) displays ferromagnetic and antiferromagnetic competition behavior, this does not prevent the molecule from functioning as a single-molecule magnet (SMM). The SMM behavior is evidenced by observing frequency dependent out-of-phase ac signals as well as magnetization hysteresis loops at low temperatures in a micro-SQUID study. A brief comparison between all rod-like Mn
12
materials is also given in the manuscript.
A new member of rod-like Mn
12
molecules functions as a single molecule magnet.</description><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/c9ra06280g</identifier><language>eng</language><ispartof>RSC advances, 2019-11, Vol.9 (65), p.3774-37746</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Yang, En-Che</creatorcontrib><creatorcontrib>Huang, Shi-Yi</creatorcontrib><creatorcontrib>Wernsdorfer, Wolfgang</creatorcontrib><creatorcontrib>Hong, Ling-Xuan</creatorcontrib><creatorcontrib>Damjanovic, Marko</creatorcontrib><creatorcontrib>Niekamp, Lukas</creatorcontrib><creatorcontrib>Lee, Gene-Hsiang</creatorcontrib><title>A new member of a class of rod-like Mn single molecule magnets using 2-(pyridine-2-ly)propan-2-ol</title><title>RSC advances</title><description>This paper reports on the synthesis, structure and magnetic properties of a new type of rod like Mn
12
metal cluster, [Mn
12
O
7
(OH)
2
(OMe)
2
(dmhmp)
4
(O
2
CPh)
11
(H
2
O)] (
6
) where the ligand (dmhmpH) is 2-(pyridine-2-yl)propan-2-ol. Compound (
6
) was obtained by reacting MnCl
2
·4H
2
O with dmhmpH in the presence of benzoic salt and Et
3
N. The resulting crystalline material is assigned to the triclinic space group
P
1&cmb.macr;. Although compound (
6
) displays ferromagnetic and antiferromagnetic competition behavior, this does not prevent the molecule from functioning as a single-molecule magnet (SMM). The SMM behavior is evidenced by observing frequency dependent out-of-phase ac signals as well as magnetization hysteresis loops at low temperatures in a micro-SQUID study. A brief comparison between all rod-like Mn
12
materials is also given in the manuscript.
A new member of rod-like Mn
12
molecules functions as a single molecule magnet.</description><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFjrEKwjAURYMgKOriLjw3HaJpqsGOIoqLm3uJ7WuJpklILNK_twXBTe9yDpzlEjKN2CpicbLOEi-Z4DtW9siQs42gnIlkQCYh3Fk7sY24iIZE7sHgCyqsbujBFiAh0zKETr3NqVYPhIuBoEypESqrMas7kaXBZ4C6C8DpwjVe5cog5VQ3S-etk6Z1q8ekX0gdcPLhiMxOx-vhTH3IUudVJX2Tfu_G__v8V09dXsRvBShPWA</recordid><startdate>20191120</startdate><enddate>20191120</enddate><creator>Yang, En-Che</creator><creator>Huang, Shi-Yi</creator><creator>Wernsdorfer, Wolfgang</creator><creator>Hong, Ling-Xuan</creator><creator>Damjanovic, Marko</creator><creator>Niekamp, Lukas</creator><creator>Lee, Gene-Hsiang</creator><scope/></search><sort><creationdate>20191120</creationdate><title>A new member of a class of rod-like Mn single molecule magnets using 2-(pyridine-2-ly)propan-2-ol</title><author>Yang, En-Che ; Huang, Shi-Yi ; Wernsdorfer, Wolfgang ; Hong, Ling-Xuan ; Damjanovic, Marko ; Niekamp, Lukas ; Lee, Gene-Hsiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c9ra06280g3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, En-Che</creatorcontrib><creatorcontrib>Huang, Shi-Yi</creatorcontrib><creatorcontrib>Wernsdorfer, Wolfgang</creatorcontrib><creatorcontrib>Hong, Ling-Xuan</creatorcontrib><creatorcontrib>Damjanovic, Marko</creatorcontrib><creatorcontrib>Niekamp, Lukas</creatorcontrib><creatorcontrib>Lee, Gene-Hsiang</creatorcontrib><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, En-Che</au><au>Huang, Shi-Yi</au><au>Wernsdorfer, Wolfgang</au><au>Hong, Ling-Xuan</au><au>Damjanovic, Marko</au><au>Niekamp, Lukas</au><au>Lee, Gene-Hsiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A new member of a class of rod-like Mn single molecule magnets using 2-(pyridine-2-ly)propan-2-ol</atitle><jtitle>RSC advances</jtitle><date>2019-11-20</date><risdate>2019</risdate><volume>9</volume><issue>65</issue><spage>3774</spage><epage>37746</epage><pages>3774-37746</pages><eissn>2046-2069</eissn><abstract>This paper reports on the synthesis, structure and magnetic properties of a new type of rod like Mn
12
metal cluster, [Mn
12
O
7
(OH)
2
(OMe)
2
(dmhmp)
4
(O
2
CPh)
11
(H
2
O)] (
6
) where the ligand (dmhmpH) is 2-(pyridine-2-yl)propan-2-ol. Compound (
6
) was obtained by reacting MnCl
2
·4H
2
O with dmhmpH in the presence of benzoic salt and Et
3
N. The resulting crystalline material is assigned to the triclinic space group
P
1&cmb.macr;. Although compound (
6
) displays ferromagnetic and antiferromagnetic competition behavior, this does not prevent the molecule from functioning as a single-molecule magnet (SMM). The SMM behavior is evidenced by observing frequency dependent out-of-phase ac signals as well as magnetization hysteresis loops at low temperatures in a micro-SQUID study. A brief comparison between all rod-like Mn
12
materials is also given in the manuscript.
A new member of rod-like Mn
12
molecules functions as a single molecule magnet.</abstract><doi>10.1039/c9ra06280g</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | EISSN: 2046-2069 |
| ispartof | RSC advances, 2019-11, Vol.9 (65), p.3774-37746 |
| issn | 2046-2069 |
| language | eng |
| recordid | cdi_rsc_primary_c9ra06280g |
| source | PMC (PubMed Central) |
| title | A new member of a class of rod-like Mn single molecule magnets using 2-(pyridine-2-ly)propan-2-ol |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-28T05%3A46%3A11IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-rsc&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20new%20member%20of%20a%20class%20of%20rod-like%20Mn%20single%20molecule%20magnets%20using%202-(pyridine-2-ly)propan-2-ol&rft.jtitle=RSC%20advances&rft.au=Yang,%20En-Che&rft.date=2019-11-20&rft.volume=9&rft.issue=65&rft.spage=3774&rft.epage=37746&rft.pages=3774-37746&rft.eissn=2046-2069&rft_id=info:doi/10.1039/c9ra06280g&rft_dat=%3Crsc%3Ec9ra06280g%3C/rsc%3E%3Cgrp_id%3Ecdi_FETCH-rsc_primary_c9ra06280g3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |