Suppressing photo-oxidation of non-fullerene acceptors and their blends in organic solar cells by exploring material design and employing friendly stabilizers

In addition to a high power conversion efficiency, ambient stability is another impact factor for the successful commercialization of organic solar cells (OSCs). Understanding the role of photovoltaic materials is the key to address this challenge, but no such studies have been systematically perfor...

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Bibliographic Details
Published in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2019, Vol.7 (43), p.2588-2511
Main Authors: Guo, Jing, Wu, Yao, Sun, Rui, Wang, Wei, Guo, Jie, Wu, Qiang, Tang, Xiaofeng, Sun, Chenkai, Luo, Zhenghui, Chang, Kai, Zhang, Zhuohan, Yuan, Jun, Li, Tengfei, Tang, Weihua, Zhou, Erjun, Xiao, Zuo, Ding, Liming, Zou, Yingping, Zhan, Xiaowei, Yang, Chuluo, Li, Zhen, Brabec, Christoph J, Li, Yongfang, Min, Jie
Format: Article
Language:English
Subjects:
Chelates
Commercialization
Comparative analysis
Design
Diimide
Energy conversion efficiency
Fullerenes
Investigations
Mixtures
Nickel
Optical density
Organic chemistry
Oxidation
Photobleaching
Photooxidation
Photovoltaic cells
Photovoltaics
Solar cells
Stability
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Summary:In addition to a high power conversion efficiency, ambient stability is another impact factor for the successful commercialization of organic solar cells (OSCs). Understanding the role of photovoltaic materials is the key to address this challenge, but no such studies have been systematically performed on non-fullerene acceptors (NFAs). In this work, we firstly investigate the role of NFA photo-oxidation in device degradation. Relevant investigation of physical dynamics underlines the effects on the device performance for NFA photo-oxidation acting as trap states in exposed blends. In addition, taking ITIC as an example, we shed some light on the possible mechanisms of NFA photo-oxidation, which cannot be eliminated by relevant strategies and principles of material design. These results drive us to further investigate the photobleaching rates of thirty-three NFAs, including fused-ring electron acceptors and perylene diimide acceptor derivatives. Surprisingly, most of them show a higher optical density loss as compared to their fullerene-based counterparts. In view of relevant comparative analysis in the Discussion section, we further propose some design strategies to improve the photo-oxidation stability of NFAs. More importantly, we also find a stabilizer (namely nickel chelate S6) that can effectively suppress the photo-oxidation of NFAs and their blends and thus improve the ambient stability of OSCs. Rational material design and additive selection boost the longevity of high-efficiency non-fullerene solar cells against photo-oxidation.
ISSN:2050-7488
2050-7496
DOI:10.1039/c9ta09961a