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Defect-induced broadband photodetection of layered γ-InSe nanofilm and its application in near infrared image sensors

In this study, we report on the synthesis of layered γ-In 2 Se 3 for broadband photodetector and near infrared light image sensing applications. The layered γ-In 2 Se 3 nanofilm with a thickness of around 74 nm was deposited onto a n-Si wafer through radio frequency magnetron sputtering. It is found...

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Published in:Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2019-09, Vol.7 (37), p.11532-11539
Main Authors: Wu, Chun-Yan, Kang, Jing-Wei, Wang, Bin, Zhu, Hui-Nan, Li, Zhong-Jun, Chen, Shi-Rong, Wang, Li, Yang, Wen-Hua, Xie, Chao, Luo, Lin-Bao
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Summary:In this study, we report on the synthesis of layered γ-In 2 Se 3 for broadband photodetector and near infrared light image sensing applications. The layered γ-In 2 Se 3 nanofilm with a thickness of around 74 nm was deposited onto a n-Si wafer through radio frequency magnetron sputtering. It is found that the as-assembled γ-In 2 Se 3 /n-Si shows an obvious photovoltaic behavior and can work properly as a self-powered broadband photodetector over a wide range of wavelengths (200-2200 nm). Such a unique spectral response beyond the absorption limit of both intrinsic γ-In 2 Se 3 and n-Si can be ascribed to the existence of defect energy levels between the valence band and the conduction band, as a result of Se substitution of In atoms according to theoretical simulation based on first-principles calculations. Specifically, the γ-In 2 Se 3 /n-Si photodetector has a responsivity of 0.57 A W −1 , a specific detectivity of 2.6 × 10 12 Jones and a fast response speed (35/115 μs for τ r / τ f ) under 808 nm light illumination, respectively, which are slightly better or comparable to other devices with similar geometries. Lastly, it was revealed that the γ-In 2 Se 3 /n-Si heterojunction photodetector can function as an effective near infrared (NIR) light image sensor with a decent spatial resolution, which suggests the great potential of the current device in future NIR optoelectronic systems. We report on the synthesis of layered γ-In 2 Se 3 nanofilm for broadband photodetector and near infrared light image sensing applications.
ISSN:2050-7526
2050-7534
DOI:10.1039/c9tc04322e