Rational regulation of transition metals in polyoxometalate hybrids without noble metal assistance for efficient light-driven H production

Four new rationally designed polyoxometalate (POM)-based hybrids are reported with a maximum photocatalytic hydrogen evolution rate of 12245.59 μmol g −1 h −1 , which outperform all known POM-based metal-organic photocatalysts. Four new noble metal-free hybrids are reported with a maximum photocatal...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2020-07, Vol.56 (52), p.7199-722
Main Authors: Li, Bonan, Yu, Xiaojing, Pang, Haijun, Shen, Qingbo, Hou, Yan, Ma, Huiyuan, Xin, Jianjiao
Format: Article
Language:English
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Summary:Four new rationally designed polyoxometalate (POM)-based hybrids are reported with a maximum photocatalytic hydrogen evolution rate of 12245.59 μmol g −1 h −1 , which outperform all known POM-based metal-organic photocatalysts. Four new noble metal-free hybrids are reported with a maximum photocatalytic hydrogen evolution rate of 12245.59 μmol g −1 h −1 , which outperform all known polyoxometalate (POM)-based metal-organic photocatalysts.
ISSN:1359-7345
1364-548X
DOI:10.1039/d0cc00846j