A heterodinuclear, formal AuPt complex with weakly bound alkene ligands

[(Ph 3 P)AuPt(nbe) 3 ][BAr 4 F ] (nbe = norbornene) constitutes the first olefin-containing, formal Au +I Pt 0 complex. The unusual coordination mode and the electronic properties have been analyzed spectroscopically and by calculations. The low binding energy of the nbe ligands make this complex a...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2020-05, Vol.56 (4), p.535-5353
Main Authors: Ernst, Lukas D, Koessler, Konstantin, Peter, Andreas, Kratzert, Daniel, Scherer, Harald, Butschke, Burkhard
Format: Article
Language:English
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Summary:[(Ph 3 P)AuPt(nbe) 3 ][BAr 4 F ] (nbe = norbornene) constitutes the first olefin-containing, formal Au +I Pt 0 complex. The unusual coordination mode and the electronic properties have been analyzed spectroscopically and by calculations. The low binding energy of the nbe ligands make this complex a valuable precursor for formal Au +I Pt 0 complexes and a candidate for heterobimetallic catalysis. Due to the weakly bound alkene ligands, [(Ph 3 P)AuPt(nbe) 3 ][BAr 4 F ] can serve as a precursor for the synthesis of formal Au +I Pt 0 complexes.
ISSN:1359-7345
1364-548X
DOI:10.1039/d0cc01719a