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Unravelling the local structure of catalytic Fe-oxo clusters stabilized on the MOF-808 metal organic-framework
Stabilizing catalytic iron-oxo-clusters within nanoporous metal-organic frameworks (MOFs) is a powerful strategy to prepare new active materials for the degradation of toxic chemicals, such as bisphenol A. Herein, we combine pair distribution function analysis of total X-ray scattering data and X-ra...
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Published in: | Chemical communications (Cambridge, England) England), 2020-12, Vol.56 (1), p.15615-15618 |
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Main Authors: | , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Stabilizing catalytic iron-oxo-clusters within nanoporous metal-organic frameworks (MOFs) is a powerful strategy to prepare new active materials for the degradation of toxic chemicals, such as bisphenol A. Herein, we combine pair distribution function analysis of total X-ray scattering data and X-ray absorption spectroscopy, with computational modelling to understand the local structural nature of added redox-active iron-oxo clusters bridging neighbouring zirconia-nodes within MOF-808.
Advanced synchrotron characterization and computational modelling are applied to understand the local structure of added redox-active iron-oxo clusters bridging zirconia-nodes within MOF-808. |
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ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/d0cc06134d |