Precise design and synthesis of Pd/InO@CoO core-shell nanofibers for the highly efficient catalytic combustion of toluene

• Published in: Nanoscale 2020-06, Vol.12 (22), p.12133-12145
• Main Authors: Du, Xuebi, Dong, Fang, Tang, Zhicheng, Zhang, Jiyi
• Format: Article
• Language: English
• ISSN: 2040-3364; 2040-3372
• DOI: 10.1039/d0nr02334e

In this work, Pd/InO x @CoO x core-shell nanofibers, CoO x @Pd/InO x core-shell nanofibers and Pd/InO x /CoO x nanofibers with different morphologies have been successfully synthesized for the catalytic combustion of toluene. Among them, the Pd/InO x @CoO x core-shell sample is novel and composed of Pd/InO x nanotube cores, CoO x nanocubes and CoO x nanoparticle shells derived from ZIF-67. On the contrary, the CoO x @Pd/InO x core-shell catalyst is assembled by CoO x nanocube cores and Pd/InO x nanotube shells. Finally, the Pd/InO x /CoO x nanofibers as references are synthesized by a method similar to the synthesis of the CoO x @Pd/InO x core-shell sample. Interestingly, the Pd/InO x @CoO x core-shell sample displayed the best activity for toluene oxidation with T 90 = 253 °C, good thermal stability and good cyclic stability during three runs. Through some characterizations, it was verified that the Pd/InO x @CoO x core-shell sample exhibited the best performance for toluene oxidation reactions due to a larger specific surface area, higher reducibility, more abundant structural defects and oxygen vacancies, higher proportion of Pd 0 and Co 3+ species and higher lattice oxygen species than others. Simultaneously, the Pd/InO x @CoO x core-shell sample exhibited good thermal stability and cyclic stability, which might be due to the layer of the CoO x shell to protect the stability of the Pd nanoparticle core. In this work, Pd/InO x @CoO x core-shell nanofibers, CoO x @Pd/InO x core-shell nanofibers and Pd/InO x /CoO x nanofibers with different morphologies have been successfully synthesized for the catalytic combustion of toluene.