A novel CoFeO@Cr-MIL-101/Y zeolite ternary nanocomposite as a magnetically separable sonocatalyst for efficient sonodegradation of organic dye contaminants from water

• Published in: RSC advances 2020-03, Vol.1 (17), p.182-196
• Main Authors: Sadeghi, Meysam, Farhadi, Saeed, Zabardasti, Abedin
• Format: Article
• Language: English
• ISSN: 2046-2069
• DOI: 10.1039/d0ra00877j

In this research, a novel magnetic sonocatalyst nanocomposite, CoFe 2 O 4 @Cr-MIL-101/Y zeolite, has been successfully fabricated employing a simple hydrothermal method. The as-prepared catalyst was thoroughly identified using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), energy dispersive X-ray spectroscopy (EDS), EDS elemental dot-mapping, transmission electron microscopy (TEM), atomic force microscopy (AFM), vibrating sample magnetometer (VSM), and nitrogen Brunauer-Emmett-Teller (N 2 -BET) analyses. The procured CoFe 2 O 4 @Cr-MIL-101/Y nanocomposite was then assessed for the decomposition of three types of organic dyes namely methylene blue (MB), rhodamine B (RhB) and methyl orange (MO) from water solution using ultrasound irradiation and subsequently monitored via UV-Vis absorption technique. The sonodecomposition reactions of organic dyes were accomplished in the presence of the H 2 O 2 solution as a green oxidizing agent. Furthermore, the influence of various experimental independent factors such as irradiation time, process type, initial dye concentration, catalyst dosage, H 2 O 2 concentration, scavenger type, and catalyst regeneration on the decomposition of MB, RhB and MO were surveyed. Additionally, a first order kinetic model was applied to investigate the sonodecomposition reactions of dye contaminants. The rate constant ( k ) and half-life ( t 1/2 ) data were gained as 0.0675 min −1 and 10.2666 min, respectively, for the decomposition of MB in the US/H 2 O 2 /CoFe 2 O 4 @Cr-MIL-101/Y system. Besides, evaluating the attained results, the distinctive performance of &z.rad;OH as the radical scavenger originating from H 2 O 2 throughout the sonodecomposition process is vividly approved. A novel magnetically separable CoFe 2 O 4 @Cr-MIL-101/Y zeolite ternary nanocomposite was prepared and applied as a sonocatalyst for efficient degradation of organic contaminants.