Bio-elastomers based on polyocimene synthesized coordination polymerization using neodymium-based catalytic systems

Towards the development of eco-friendly alternatives of elastomeric materials, which can replace petroleum-based materials, it is crucial to explore different monomers and catalytic systems in order to find the best possible combinations for specific applications. Herein, we report the synthesis of...

Full description

Saved in:
Bibliographic Details
Published in:RSC advances 2020-10, Vol.1 (6), p.36539-36545
Main Authors: Valencia, Luis, Enríquez-Medrano, Francisco Javier, López González, Héctor Ricardo, Handa, Rishab, Caballero, Hened Saade, Carrizales, Ricardo Mendoza, Olivares-Romero, José Luis, Díaz de León Gómez, Ramón Enrique
Format: Article
Language:English
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page 36545
container_issue 6
container_start_page 36539
container_title RSC advances
container_volume 1
creator Valencia, Luis
Enríquez-Medrano, Francisco Javier
López González, Héctor Ricardo
Handa, Rishab
Caballero, Hened Saade
Carrizales, Ricardo Mendoza
Olivares-Romero, José Luis
Díaz de León Gómez, Ramón Enrique
description Towards the development of eco-friendly alternatives of elastomeric materials, which can replace petroleum-based materials, it is crucial to explore different monomers and catalytic systems in order to find the best possible combinations for specific applications. Herein, we report the synthesis of polyocimene via coordination polymerization using two different neodymium-based catalysts (NdV 3 and Nd(Oi-Pr) 3 ), activated by alkylaluminums/organoboron compounds. By varying the type of co-catalyst species, halide donors, and reaction parameters, we have demonstrated the possibility to obtain polymers with a controlled microstructure and tunable properties, in terms of molecular weight characteristics and kinetics. Our results provide important insights towards the search for the optimum catalytic system to produce bio-elastomers. Towards the development of eco-friendly alternatives of elastomeric materials, herein we report the synthesis of polyocimene via coordination polymerization.
doi_str_mv 10.1039/d0ra06583h
format article
fullrecord <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_d0ra06583h</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>d0ra06583h</sourcerecordid><originalsourceid>FETCH-rsc_primary_d0ra06583h3</originalsourceid><addsrcrecordid>eNqFj0EKwjAQRYMgKNqNeyEeoJq2GnSrKB7AfYnJqCNNUjJxEU9vQcGdzmYY3p8Hn7FJIeaFqDYLI4IScrWubj02LMVS5qWQmwHLiO6iG7kqSlkMGW3R59Aoit5CIH5WBIZ7x1vfJK_RggNOycUbED47pL0PBp2K-Al1b_h8nw9Cd-UOvEkWHzZ_y7SKqkkRdeehCJbGrH9RDUH22SM2PexPu2MeSNdtQKtCqr8FqhGb_eJ1ay7VP8cLe4ladQ</addsrcrecordid><sourcetype>Enrichment Source</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Bio-elastomers based on polyocimene synthesized coordination polymerization using neodymium-based catalytic systems</title><source>PubMed Central Free</source><creator>Valencia, Luis ; Enríquez-Medrano, Francisco Javier ; López González, Héctor Ricardo ; Handa, Rishab ; Caballero, Hened Saade ; Carrizales, Ricardo Mendoza ; Olivares-Romero, José Luis ; Díaz de León Gómez, Ramón Enrique</creator><creatorcontrib>Valencia, Luis ; Enríquez-Medrano, Francisco Javier ; López González, Héctor Ricardo ; Handa, Rishab ; Caballero, Hened Saade ; Carrizales, Ricardo Mendoza ; Olivares-Romero, José Luis ; Díaz de León Gómez, Ramón Enrique</creatorcontrib><description>Towards the development of eco-friendly alternatives of elastomeric materials, which can replace petroleum-based materials, it is crucial to explore different monomers and catalytic systems in order to find the best possible combinations for specific applications. Herein, we report the synthesis of polyocimene via coordination polymerization using two different neodymium-based catalysts (NdV 3 and Nd(Oi-Pr) 3 ), activated by alkylaluminums/organoboron compounds. By varying the type of co-catalyst species, halide donors, and reaction parameters, we have demonstrated the possibility to obtain polymers with a controlled microstructure and tunable properties, in terms of molecular weight characteristics and kinetics. Our results provide important insights towards the search for the optimum catalytic system to produce bio-elastomers. Towards the development of eco-friendly alternatives of elastomeric materials, herein we report the synthesis of polyocimene via coordination polymerization.</description><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/d0ra06583h</identifier><language>eng</language><ispartof>RSC advances, 2020-10, Vol.1 (6), p.36539-36545</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Valencia, Luis</creatorcontrib><creatorcontrib>Enríquez-Medrano, Francisco Javier</creatorcontrib><creatorcontrib>López González, Héctor Ricardo</creatorcontrib><creatorcontrib>Handa, Rishab</creatorcontrib><creatorcontrib>Caballero, Hened Saade</creatorcontrib><creatorcontrib>Carrizales, Ricardo Mendoza</creatorcontrib><creatorcontrib>Olivares-Romero, José Luis</creatorcontrib><creatorcontrib>Díaz de León Gómez, Ramón Enrique</creatorcontrib><title>Bio-elastomers based on polyocimene synthesized coordination polymerization using neodymium-based catalytic systems</title><title>RSC advances</title><description>Towards the development of eco-friendly alternatives of elastomeric materials, which can replace petroleum-based materials, it is crucial to explore different monomers and catalytic systems in order to find the best possible combinations for specific applications. Herein, we report the synthesis of polyocimene via coordination polymerization using two different neodymium-based catalysts (NdV 3 and Nd(Oi-Pr) 3 ), activated by alkylaluminums/organoboron compounds. By varying the type of co-catalyst species, halide donors, and reaction parameters, we have demonstrated the possibility to obtain polymers with a controlled microstructure and tunable properties, in terms of molecular weight characteristics and kinetics. Our results provide important insights towards the search for the optimum catalytic system to produce bio-elastomers. Towards the development of eco-friendly alternatives of elastomeric materials, herein we report the synthesis of polyocimene via coordination polymerization.</description><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFj0EKwjAQRYMgKNqNeyEeoJq2GnSrKB7AfYnJqCNNUjJxEU9vQcGdzmYY3p8Hn7FJIeaFqDYLI4IScrWubj02LMVS5qWQmwHLiO6iG7kqSlkMGW3R59Aoit5CIH5WBIZ7x1vfJK_RggNOycUbED47pL0PBp2K-Al1b_h8nw9Cd-UOvEkWHzZ_y7SKqkkRdeehCJbGrH9RDUH22SM2PexPu2MeSNdtQKtCqr8FqhGb_eJ1ay7VP8cLe4ladQ</recordid><startdate>20201005</startdate><enddate>20201005</enddate><creator>Valencia, Luis</creator><creator>Enríquez-Medrano, Francisco Javier</creator><creator>López González, Héctor Ricardo</creator><creator>Handa, Rishab</creator><creator>Caballero, Hened Saade</creator><creator>Carrizales, Ricardo Mendoza</creator><creator>Olivares-Romero, José Luis</creator><creator>Díaz de León Gómez, Ramón Enrique</creator><scope/></search><sort><creationdate>20201005</creationdate><title>Bio-elastomers based on polyocimene synthesized coordination polymerization using neodymium-based catalytic systems</title><author>Valencia, Luis ; Enríquez-Medrano, Francisco Javier ; López González, Héctor Ricardo ; Handa, Rishab ; Caballero, Hened Saade ; Carrizales, Ricardo Mendoza ; Olivares-Romero, José Luis ; Díaz de León Gómez, Ramón Enrique</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_d0ra06583h3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Valencia, Luis</creatorcontrib><creatorcontrib>Enríquez-Medrano, Francisco Javier</creatorcontrib><creatorcontrib>López González, Héctor Ricardo</creatorcontrib><creatorcontrib>Handa, Rishab</creatorcontrib><creatorcontrib>Caballero, Hened Saade</creatorcontrib><creatorcontrib>Carrizales, Ricardo Mendoza</creatorcontrib><creatorcontrib>Olivares-Romero, José Luis</creatorcontrib><creatorcontrib>Díaz de León Gómez, Ramón Enrique</creatorcontrib><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Valencia, Luis</au><au>Enríquez-Medrano, Francisco Javier</au><au>López González, Héctor Ricardo</au><au>Handa, Rishab</au><au>Caballero, Hened Saade</au><au>Carrizales, Ricardo Mendoza</au><au>Olivares-Romero, José Luis</au><au>Díaz de León Gómez, Ramón Enrique</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Bio-elastomers based on polyocimene synthesized coordination polymerization using neodymium-based catalytic systems</atitle><jtitle>RSC advances</jtitle><date>2020-10-05</date><risdate>2020</risdate><volume>1</volume><issue>6</issue><spage>36539</spage><epage>36545</epage><pages>36539-36545</pages><eissn>2046-2069</eissn><abstract>Towards the development of eco-friendly alternatives of elastomeric materials, which can replace petroleum-based materials, it is crucial to explore different monomers and catalytic systems in order to find the best possible combinations for specific applications. Herein, we report the synthesis of polyocimene via coordination polymerization using two different neodymium-based catalysts (NdV 3 and Nd(Oi-Pr) 3 ), activated by alkylaluminums/organoboron compounds. By varying the type of co-catalyst species, halide donors, and reaction parameters, we have demonstrated the possibility to obtain polymers with a controlled microstructure and tunable properties, in terms of molecular weight characteristics and kinetics. Our results provide important insights towards the search for the optimum catalytic system to produce bio-elastomers. Towards the development of eco-friendly alternatives of elastomeric materials, herein we report the synthesis of polyocimene via coordination polymerization.</abstract><doi>10.1039/d0ra06583h</doi><tpages>7</tpages></addata></record>
fulltext fulltext
identifier EISSN: 2046-2069
ispartof RSC advances, 2020-10, Vol.1 (6), p.36539-36545
issn 2046-2069
language eng
recordid cdi_rsc_primary_d0ra06583h
source PubMed Central Free
title Bio-elastomers based on polyocimene synthesized coordination polymerization using neodymium-based catalytic systems
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-28T19%3A39%3A51IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-rsc&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Bio-elastomers%20based%20on%20polyocimene%20synthesized%20coordination%20polymerization%20using%20neodymium-based%20catalytic%20systems&rft.jtitle=RSC%20advances&rft.au=Valencia,%20Luis&rft.date=2020-10-05&rft.volume=1&rft.issue=6&rft.spage=36539&rft.epage=36545&rft.pages=36539-36545&rft.eissn=2046-2069&rft_id=info:doi/10.1039/d0ra06583h&rft_dat=%3Crsc%3Ed0ra06583h%3C/rsc%3E%3Cgrp_id%3Ecdi_FETCH-rsc_primary_d0ra06583h3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true