Unravelling moisture-induced CO chemisorption mechanisms in amine-modified sorbents at the molecular scale

• Published in: Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2021-03, Vol.9 (9), p.5542-5555
• Main Authors: Sardo, Mariana, Afonso, Rui, Ju ków, Joanna, Pacheco, Marlene, Bordonhos, Marta, Pinto, Moisés L, Gomes, José R. B, Mafra, Luís
• Format: Article
• ISSN: 2050-7488; 2050-7496
• DOI: 10.1039/d0ta09808f

This work entails a comprehensive solid-state NMR and computational study of the influence of water and CO 2 partial pressures on the CO 2 -adducts formed in amine-grafted silica sorbents. Our approach provides atomic level insights on hypothesised mechanisms for CO 2 capture under dry and wet conditions in a tightly controlled atmosphere. The method used for sample preparation avoids the use of liquid water slurries, as performed in previous studies, enabling a molecular level understanding, by NMR, of the influence of controlled amounts of water vapor (down to ca. 0.7 kPa) in CO 2 chemisorption processes. Details on the formation mechanism of moisture-induced CO 2 species are provided aiming to study CO 2  : H 2 O binary mixtures in amine-grafted silica sorbents. The interconversion between distinct chemisorbed CO 2 species was quantitatively monitored by NMR under wet and dry conditions in silica sorbents grafted with amines possessing distinct bulkiness (primary and tertiary). Particular attention was given to two distinct carbonyl environments resonating at δ C ∼161 and 155 ppm, as their presence and relative intensities are greatly affected by moisture depending on the experimental conditions. 1D and 2D NMR spectral assignments of both these 13 C resonances were assisted by density functional theory calculations of 1 H and 13 C chemical shifts on model structures of alkylamines grafted onto the silica surface that validated various hydrogen-bonded CO 2 species that may occur upon formation of bicarbonate, carbamic acid and alkylammonium carbamate ion pairs. Water is a key component in flue gas streams, playing a major role in CO 2 speciation, and this work extends the current knowledge on chemisorbed CO 2 structures and their stabilities under dry/wet conditions, on amine-modified solid surfaces. Solid-state NMR and molecular modeling provide structural insights on the influence of water upon CO 2 chemisorption on primary and tertiary amine-grafted mesoporous silica sorbent materials.