Synthesis of bifunctional disiloxanes subsequent hydrosilylation of alkenes and alkynes

The first protocol for the synthesis of unsymmetrical bifunctional 1,1,3,3-tetramethyldisiloxane derivatives via subsequent hydrosilylation of alkenes and alkynes is presented. The methodology described has vast functional group tolerance and is extremely efficient towards the formation of novel dis...

Full description

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2021-05, Vol.57 (37), p.454-457
Main Authors: Szyling, Jakub, Januszewski, Rafa, Jankowska, Kamila, Walkowiak, J drzej, Kownacki, Ireneusz, Franczyk, Adrian
Format: Article
Language:
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The first protocol for the synthesis of unsymmetrical bifunctional 1,1,3,3-tetramethyldisiloxane derivatives via subsequent hydrosilylation of alkenes and alkynes is presented. The methodology described has vast functional group tolerance and is extremely efficient towards the formation of novel disiloxane-based building blocks. Synthesis of unsymmetrical and bifunctional building blocks based on 1,1,3,3-tetramethyldisiloxane is presented which allows compounds with a wide spectrum of reactive groups bonded to alkenes and alkynes to be obtained.
ISSN:1359-7345
1364-548X
DOI:10.1039/d1cc01253c