coordinated Ru cation: a robust catalyst for aerobic oxidations of benzylamine and benzyl alcohol

A stable ionic κ 2 Sn , P -coordinated Ru complex shows excellent catalytic activity in aerobic oxidations of benzylamine and benzyl alcohol. This complex is stabilized by a stannylene-phosphine peri -substituted naphthalene ligand, which can act as either a reducing agent for a Ru( iii ) complex or...

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Published in:Chemical communications (Cambridge, England) England), 2021-12, Vol.57 (96), p.12992-12995
Main Authors: Aman, Michal, Dostál, Libor, R i ka, Aleš, Tydlitát, Ji í, Beckmann, Jens, Turek, Jan, Jambor, Roman
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Summary:A stable ionic κ 2 Sn , P -coordinated Ru complex shows excellent catalytic activity in aerobic oxidations of benzylamine and benzyl alcohol. This complex is stabilized by a stannylene-phosphine peri -substituted naphthalene ligand, which can act as either a reducing agent for a Ru( iii ) complex or as a κ 2 Sn , P -chelating ligand for Ru( ii ) compounds. A stable ionic κ 2 Sn , P -coordinated Ru complex was used as an efficient catalyst for aerobic oxidation reactions.
ISSN:1359-7345
1364-548X
DOI:10.1039/d1cc06173a