Loading…

Compositional heterogeneity in CsFAPb(BrI) perovskite films and its impact on phase behavior

Hybrid organic inorganic lead halide perovskite semiconductors of the form Cs y FA 1− y Pb(Br x I 1− x ) 3 are promising candidate materials for high-efficiency photovoltaics. Notably, cation and anion substitution can be used to tune the band gaps to optimize performance and improve stability. Howe...

Full description

Saved in:
Bibliographic Details
Published in:Energy & environmental science 2021-12, Vol.14 (12), p.6394-645
Main Authors: Barrier, Julien, Beal, Rachel E, Gold-Parker, Aryeh, Vigil, Julian A, Wolf, Eli, Waquier, Louis, Weadock, Nicholas J, Zhang, Zihan, Schelhas, Laura T, Nogueira, Ana Flavia, McGehee, Michael D, Toney, Michael F
Format: Article
Language:
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Hybrid organic inorganic lead halide perovskite semiconductors of the form Cs y FA 1− y Pb(Br x I 1− x ) 3 are promising candidate materials for high-efficiency photovoltaics. Notably, cation and anion substitution can be used to tune the band gaps to optimize performance and improve stability. However, multi-component materials can be prone to compositional and structural inhomogeneity and the extent, length scale and impact of this heterogeneity on lead halide perovskite properties are not well understood. Here we use synchrotron X-ray diffraction to probe the evolution of crystal structure across the tetragonal-to-cubic phase transition for a series of Cs y FA 1− y Pb(Br x I 1− x ) 3 thin films with x = 0.05 to 0.3 and y = 0.17 to 0.40. We find that the transition occurs across a broad temperature range of approximately 40 °C, much larger than for pure compounds such as MAPbI 3 and MAPbBr 3 . We hypothesize that this smearing of the phase transition is due to compositional inhomogeneities that give rise to a distribution of local transition temperatures and we estimate the composition varies by about 10% to 15% with likely greater heterogeneity for the halide anion than the cation. This approach of mapping the transition is a simple and effective method of assessing heterogeneity, enabling evaluation of its impact. We study the phase behavior of hybrid organic-inorganic metal-halide perovskite and propose a simple method to assess heterogeneity in the
ISSN:1754-5692
1754-5706
DOI:10.1039/d1ee01184g