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Y(OTf)-catalyzed phosphorylation of 2-chromene hemiacetals with P(O)-H compounds to 2-phosphorylated 2-chromenes
A facile synthesis of 2-phosphorylated 2 H -chromenes has been accomplished herein via a Y(OTf) 3 -catalyzed dehydrative coupling of 2 H -chromene hemiacetals with P(O)-H compounds. This protocol features low catalyst loading, mild reaction conditions, broad substrate scope and easy elaboration of t...
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| Published in: | Organic & biomolecular chemistry 2021-08, Vol.19 (31), p.6812-6816 |
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| Main Authors: | , , , , , |
| Format: | Article |
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| container_end_page | 6816 |
| container_issue | 31 |
| container_start_page | 6812 |
| container_title | Organic & biomolecular chemistry |
| container_volume | 19 |
| creator | Zheng, Shi-Lu Zou, Yun-Xiang Wen, Zhong Lin, Jia-Fu Gu, Ling-Hui Chen, Long |
| description | A facile synthesis of 2-phosphorylated 2
H
-chromenes has been accomplished herein
via
a Y(OTf)
3
-catalyzed dehydrative coupling of 2
H
-chromene hemiacetals with P(O)-H compounds. This protocol features low catalyst loading, mild reaction conditions, broad substrate scope and easy elaboration of the products.
A highly efficient dehydrative phosphorylation of 2
H
-chromene hemiacetals with P(O)-H compounds was reported, which provides 2-phosphorylated 2
H
-chromenes in rich diversity with up to 98% yield. |
| doi_str_mv | 10.1039/d1ob01221e |
| format | article |
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H
-chromenes has been accomplished herein
via
a Y(OTf)
3
-catalyzed dehydrative coupling of 2
H
-chromene hemiacetals with P(O)-H compounds. This protocol features low catalyst loading, mild reaction conditions, broad substrate scope and easy elaboration of the products.
A highly efficient dehydrative phosphorylation of 2
H
-chromene hemiacetals with P(O)-H compounds was reported, which provides 2-phosphorylated 2
H
-chromenes in rich diversity with up to 98% yield.</description><identifier>ISSN: 1477-0520</identifier><identifier>EISSN: 1477-0539</identifier><identifier>DOI: 10.1039/d1ob01221e</identifier><ispartof>Organic & biomolecular chemistry, 2021-08, Vol.19 (31), p.6812-6816</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Zheng, Shi-Lu</creatorcontrib><creatorcontrib>Zou, Yun-Xiang</creatorcontrib><creatorcontrib>Wen, Zhong</creatorcontrib><creatorcontrib>Lin, Jia-Fu</creatorcontrib><creatorcontrib>Gu, Ling-Hui</creatorcontrib><creatorcontrib>Chen, Long</creatorcontrib><title>Y(OTf)-catalyzed phosphorylation of 2-chromene hemiacetals with P(O)-H compounds to 2-phosphorylated 2-chromenes</title><title>Organic & biomolecular chemistry</title><description>A facile synthesis of 2-phosphorylated 2
H
-chromenes has been accomplished herein
via
a Y(OTf)
3
-catalyzed dehydrative coupling of 2
H
-chromene hemiacetals with P(O)-H compounds. This protocol features low catalyst loading, mild reaction conditions, broad substrate scope and easy elaboration of the products.
A highly efficient dehydrative phosphorylation of 2
H
-chromene hemiacetals with P(O)-H compounds was reported, which provides 2-phosphorylated 2
H
-chromenes in rich diversity with up to 98% yield.</description><issn>1477-0520</issn><issn>1477-0539</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFjz0LwjAURYMoWD8WdyFjO0STtlo6i-JWhy5OJaYpibRNSSJSf70ZxLo5XN6Dd96BC8CK4A3BUbotibphEoaEj4BH4iRBeBel4-8e4imYGXPHmKTJPvZAd_WzvAoQo5bW_YuXsBPKuOi-plaqFqoKhogJrRrecih4IynjDjbwKa2AFz8L0Bky1XTq0ZYGWuX4X4lzDgKzAJPKPfPlZ87B-nTMD2ekDSs6LRuq-2KoEf27vwEVkEu1</recordid><startdate>20210811</startdate><enddate>20210811</enddate><creator>Zheng, Shi-Lu</creator><creator>Zou, Yun-Xiang</creator><creator>Wen, Zhong</creator><creator>Lin, Jia-Fu</creator><creator>Gu, Ling-Hui</creator><creator>Chen, Long</creator><scope/></search><sort><creationdate>20210811</creationdate><title>Y(OTf)-catalyzed phosphorylation of 2-chromene hemiacetals with P(O)-H compounds to 2-phosphorylated 2-chromenes</title><author>Zheng, Shi-Lu ; Zou, Yun-Xiang ; Wen, Zhong ; Lin, Jia-Fu ; Gu, Ling-Hui ; Chen, Long</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_d1ob01221e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2021</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zheng, Shi-Lu</creatorcontrib><creatorcontrib>Zou, Yun-Xiang</creatorcontrib><creatorcontrib>Wen, Zhong</creatorcontrib><creatorcontrib>Lin, Jia-Fu</creatorcontrib><creatorcontrib>Gu, Ling-Hui</creatorcontrib><creatorcontrib>Chen, Long</creatorcontrib><jtitle>Organic & biomolecular chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zheng, Shi-Lu</au><au>Zou, Yun-Xiang</au><au>Wen, Zhong</au><au>Lin, Jia-Fu</au><au>Gu, Ling-Hui</au><au>Chen, Long</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Y(OTf)-catalyzed phosphorylation of 2-chromene hemiacetals with P(O)-H compounds to 2-phosphorylated 2-chromenes</atitle><jtitle>Organic & biomolecular chemistry</jtitle><date>2021-08-11</date><risdate>2021</risdate><volume>19</volume><issue>31</issue><spage>6812</spage><epage>6816</epage><pages>6812-6816</pages><issn>1477-0520</issn><eissn>1477-0539</eissn><abstract>A facile synthesis of 2-phosphorylated 2
H
-chromenes has been accomplished herein
via
a Y(OTf)
3
-catalyzed dehydrative coupling of 2
H
-chromene hemiacetals with P(O)-H compounds. This protocol features low catalyst loading, mild reaction conditions, broad substrate scope and easy elaboration of the products.
A highly efficient dehydrative phosphorylation of 2
H
-chromene hemiacetals with P(O)-H compounds was reported, which provides 2-phosphorylated 2
H
-chromenes in rich diversity with up to 98% yield.</abstract><doi>10.1039/d1ob01221e</doi><tpages>5</tpages></addata></record> |
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| identifier | ISSN: 1477-0520 |
| ispartof | Organic & biomolecular chemistry, 2021-08, Vol.19 (31), p.6812-6816 |
| issn | 1477-0520 1477-0539 |
| language | |
| recordid | cdi_rsc_primary_d1ob01221e |
| source | Royal Society of Chemistry Journals |
| title | Y(OTf)-catalyzed phosphorylation of 2-chromene hemiacetals with P(O)-H compounds to 2-phosphorylated 2-chromenes |
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