0D hybrid indium halides with highly efficient intrinsic broadband light emissions

Two new zero-dimensional (0D) hybrid indium halides of [H 2 DMP] 2 InX 7 ·2H 2 O (X = Cl, Br) were designed based on [InX 6 ] 3− octahedra as optically active centers. Remarkably, these 0D halides display intrinsic broadband yellow-orange light emissions with highest quantum yield of 58.53% exceedin...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2022-08, Vol.58 (65), p.984-987
Main Authors: Li, Dong-Yang, Sun, Yu-Ming, Xu, Zi-Yan, Xiao, Pan-Chao, Song, Jun-Hua, Lei, Xiao-Wu, Chen, Guang, Yue, Cheng-Yang
Format: Article
Language:English
Subjects:
Broadband
Halides
Indium
Light emission
Optical activity
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Summary:Two new zero-dimensional (0D) hybrid indium halides of [H 2 DMP] 2 InX 7 ·2H 2 O (X = Cl, Br) were designed based on [InX 6 ] 3− octahedra as optically active centers. Remarkably, these 0D halides display intrinsic broadband yellow-orange light emissions with highest quantum yield of 58.53% exceeding all previously reported 0D indium halides. Two new zero-dimensional hybrid indium halides of [H 2 DMP] 2 InX 7 ·2H 2 O (X = Cl, Br) display intrinsic broadband yellow-orange light emissions with the highest quantum yield of 58.53%, which exceeds those of all previously reported 0D indium halides.
ISSN:1359-7345
1364-548X
DOI:10.1039/d2cc02148j