Ce-hydroxamate metal-organic frameworks for photocatalytic H generation

Exploring the rich coordination chemistry of Ce, here we report two new entries in the emerging category of hydroxamate-based metal-organic frameworks (MOFs). The two Ce-hydroxamate MOFs exhibited different band structures and photoelectrochemical properties based on their respective coordinative en...

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Published in:Chemical communications (Cambridge, England) England), 2022-12, Vol.58 (97), p.1353-1356
Main Authors: Feng, Xuan, Li, Wenying, Yang, Lei, Song, Ting, Xia, Zhaoming, Lai, Qiuxue, Zhou, Xuemei, Xiao, Hai, Liu, Chong
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Summary:Exploring the rich coordination chemistry of Ce, here we report two new entries in the emerging category of hydroxamate-based metal-organic frameworks (MOFs). The two Ce-hydroxamate MOFs exhibited different band structures and photoelectrochemical properties based on their respective coordinative environments and overall structures, leading to varied H 2 generation performances. Exploring the rich coordination chemistry of cerium, two new hydroxamate MOFs are reported, featuring distinct band structures and photoelectrochemical properties for H 2 generation.
ISSN:1359-7345
1364-548X
DOI:10.1039/d2cc05189c